Journal of Radioanalytical and Nuclear Chemistry, volume 318, issue 3, pages 1901-1911
Role of anions in radiation-induced transformations of 18-crown-6 complexes with barium salts: simulating the effects of extraction mechanism on radiation stability of macrocyclic extractants
Publication type: Journal Article
Publication date: 2018-08-14
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor: 1.6
ISSN: 02365731, 15882780
Spectroscopy
Analytical Chemistry
Health, Toxicology and Mutagenesis
Public Health, Environmental and Occupational Health
Pollution
Radiology Nuclear Medicine and imaging
Nuclear Energy and Engineering
Abstract
Complexes of 18-crown-6 with BaCl2, Ba(NO3)2 and Ba(NTf2)2 salts were synthesized and irradiated with X-rays to simulate the radiation degradation of a macrocyclic component of extractants based on crown ether solutions in commonly used solvents. Structures and post-irradiation transformations of radical products stabilized in these complexes at 77 K were studied using EPR spectroscopy, and the mechanism of their formation and decay was proposed. Differences in ionization potentials of the macrocycle and the anions and reactivity of the intermediates generated from the anions are of importance for radiation stability of the studied compounds. The nitrate-anions was demonstrated to protect 18C6 from destruction whereas Cl− and bis(trifluoromethylsulfonyl)imide-anions can impair the radiation stability of the macrocycle. The results of the present study offer an opportunity to predict the radiation stability of the crown ether extractants and their applicability for liquid radioactive waste reprocessing.
Citations by journals
|
1
2
3
|
|
|
Radiation Physics and Chemistry
|
Radiation Physics and Chemistry
3 publications, 75%
|
|
Russian Chemical Bulletin
|
Russian Chemical Bulletin
1 publication, 25%
|
|
1
2
3
|
Citations by publishers
|
1
2
3
|
|
|
Elsevier
|
Elsevier
3 publications, 75%
|
|
Springer Nature
|
Springer Nature
1 publication, 25%
|
|
1
2
3
|
- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2019,2020,2021,2022],"ids":[0,0,0,0],"codes":[0,0,0,0],"imageUrls":["","","",""],"datasets":[{"label":"Citations number","data":[1,2,0,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["25","50",0,"25"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Radiation Physics and Chemistry","Russian Chemical Bulletin"],"ids":[14769,10918],"codes":[0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp"],"datasets":[{"label":"","data":[3,1],"backgroundColor":["#3B82F6","#3B82F6"],"percentage":[75,25],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Elsevier","Springer Nature"],"ids":[17,8],"codes":[0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp"],"datasets":[{"label":"","data":[3,1],"backgroundColor":["#3B82F6","#3B82F6"],"percentage":[75,25],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Metrics
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Nesterov S. V. et al. Role of anions in radiation-induced transformations of 18-crown-6 complexes with barium salts: simulating the effects of extraction mechanism on radiation stability of macrocyclic extractants // Journal of Radioanalytical and Nuclear Chemistry. 2018. Vol. 318. No. 3. pp. 1901-1911.
GOST all authors (up to 50)
Copy
Nesterov S. V., Zakurdaeva O. A., Kurkin T. S., Feldman V. I. Role of anions in radiation-induced transformations of 18-crown-6 complexes with barium salts: simulating the effects of extraction mechanism on radiation stability of macrocyclic extractants // Journal of Radioanalytical and Nuclear Chemistry. 2018. Vol. 318. No. 3. pp. 1901-1911.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1007/s10967-018-6093-9
UR - https://doi.org/10.1007%2Fs10967-018-6093-9
TI - Role of anions in radiation-induced transformations of 18-crown-6 complexes with barium salts: simulating the effects of extraction mechanism on radiation stability of macrocyclic extractants
T2 - Journal of Radioanalytical and Nuclear Chemistry
AU - Kurkin, Tikhon S
AU - Feldman, Vladimir I
AU - Nesterov, Sergey V
AU - Zakurdaeva, Olga A
PY - 2018
DA - 2018/08/14 00:00:00
PB - Springer Nature
SP - 1901-1911
IS - 3
VL - 318
SN - 0236-5731
SN - 1588-2780
ER -
Cite this
BibTex
Copy
@article{2018_Nesterov,
author = {Tikhon S Kurkin and Vladimir I Feldman and Sergey V Nesterov and Olga A Zakurdaeva},
title = {Role of anions in radiation-induced transformations of 18-crown-6 complexes with barium salts: simulating the effects of extraction mechanism on radiation stability of macrocyclic extractants},
journal = {Journal of Radioanalytical and Nuclear Chemistry},
year = {2018},
volume = {318},
publisher = {Springer Nature},
month = {aug},
url = {https://doi.org/10.1007%2Fs10967-018-6093-9},
number = {3},
pages = {1901--1911},
doi = {10.1007/s10967-018-6093-9}
}
Cite this
MLA
Copy
Nesterov, Sergey V., et al. “Role of anions in radiation-induced transformations of 18-crown-6 complexes with barium salts: simulating the effects of extraction mechanism on radiation stability of macrocyclic extractants.” Journal of Radioanalytical and Nuclear Chemistry, vol. 318, no. 3, Aug. 2018, pp. 1901-1911. https://doi.org/10.1007%2Fs10967-018-6093-9.
Profiles