Copolymers of 4-nitrophenyl methacrylate with styrene: Synthesis, characterization, and reactivity ratios
Publication type: Journal Article
Publication date: 1999-10-31
scimago Q2
wos Q3
SJR: 0.572
CiteScore: 5.8
Impact factor: 2.8
ISSN: 00218995, 10974628
Materials Chemistry
Surfaces, Coatings and Films
General Chemistry
Polymers and Plastics
Abstract
Free-radical copolymerization of 4-nitrophenyl methacrylate (NPMA) with styrene (STY) was carried out at 65°C in 2-butanone by using benzoyl peroxide (BPO) as initiator. NPMA was characterized by spectral and microelemental analysis. Homo- and copolymers were characterized by IR, 1H-, and 13C-NMR studies and their copolymer compositions were evaluated by 1H-NMR spectroscopic technique. The copolymer reactivity ratios were calculated using Fineman–Ross, Kelen–Tüdos, and extended Kelen–Tudos methods. The Q,e values for NPMA were determined by Alfrey–Price Q,e rule. Thermal properties of the homo- and copolymers were studied by thermogravimetric analysis and differential scanning calorimetry methods. © 1999 John Wiley & Sons, Inc. J Appl Polym Sci 74: 1186–1193, 1999
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Thamizharasi S., Gnanasundaram P., Balasubramanian S. Copolymers of 4-nitrophenyl methacrylate with styrene: Synthesis, characterization, and reactivity ratios // Journal of Applied Polymer Science. 1999. Vol. 74. No. 5. pp. 1186-1193.
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Thamizharasi S., Gnanasundaram P., Balasubramanian S. Copolymers of 4-nitrophenyl methacrylate with styrene: Synthesis, characterization, and reactivity ratios // Journal of Applied Polymer Science. 1999. Vol. 74. No. 5. pp. 1186-1193.
Cite this
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TY - JOUR
DO - 10.1002/(sici)1097-4628(19991031)74:5<1186::aid-app15>3.0.co;2-n
UR - https://doi.org/10.1002/(sici)1097-4628(19991031)74:5<1186::aid-app15>3.0.co;2-n
TI - Copolymers of 4-nitrophenyl methacrylate with styrene: Synthesis, characterization, and reactivity ratios
T2 - Journal of Applied Polymer Science
AU - Thamizharasi, S.
AU - Gnanasundaram, P
AU - Balasubramanian, S.
PY - 1999
DA - 1999/10/31
PB - Wiley
SP - 1186-1193
IS - 5
VL - 74
SN - 0021-8995
SN - 1097-4628
ER -
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BibTex (up to 50 authors)
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@article{1999_Thamizharasi,
author = {S. Thamizharasi and P Gnanasundaram and S. Balasubramanian},
title = {Copolymers of 4-nitrophenyl methacrylate with styrene: Synthesis, characterization, and reactivity ratios},
journal = {Journal of Applied Polymer Science},
year = {1999},
volume = {74},
publisher = {Wiley},
month = {oct},
url = {https://doi.org/10.1002/(sici)1097-4628(19991031)74:5<1186::aid-app15>3.0.co;2-n},
number = {5},
pages = {1186--1193},
doi = {10.1002/(sici)1097-4628(19991031)74:5<1186::aid-app15>3.0.co;2-n}
}
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Thamizharasi, S., et al. “Copolymers of 4-nitrophenyl methacrylate with styrene: Synthesis, characterization, and reactivity ratios.” Journal of Applied Polymer Science, vol. 74, no. 5, Oct. 1999, pp. 1186-1193. https://doi.org/10.1002/(sici)1097-4628(19991031)74:5<1186::aid-app15>3.0.co;2-n.