Phosphine‐Catalyzed Domino Annulation Reactions of o‐Aminotrifluoroacetophenone Derivatives with Morita−Baylis−Hillman Carbonates: Construction of Tetrahydrofuro[3,2‐b]indolines
1
Faculty of Chemistry and Chemical Engineering Yancheng Institute of Technology Yancheng 224051 People's Republic of China
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2
Yancheng Tongwei Solar Energy Co., Ltd Yancheng 224000 People's Republic of China
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Publication type: Journal Article
Publication date: 2024-04-24
scimago Q1
wos Q1
SJR: 0.930
CiteScore: 8.0
Impact factor: 4.0
ISSN: 16154150, 16154169
General Chemistry
Abstract
The domino annulation reactions of o‐aminotrifluoroacetophenone derivatives and MBH carbonates enabled by PPh3 have been reported, which provide a series of tetrahydrofuro[3,2‐b]indolines containing a CF3‐substituted tetrasubstituted carbon stereocenters in yields of 74 to 95% and >20:1 dr. In this process, MBH carbonates were used as C1/C3 synthons. The MTT assay shows that the products exhibit the activity of inhibitory effect on proliferation on Hela cancer cell line.
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Zhu Y. et al. Phosphine‐Catalyzed Domino Annulation Reactions of o‐Aminotrifluoroacetophenone Derivatives with Morita−Baylis−Hillman Carbonates: Construction of Tetrahydrofuro[3,2‐b]indolines // Advanced Synthesis and Catalysis. 2024. Vol. 366. No. 10. pp. 2252-2256.
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Zhu Y., Zhao H., Li Q., Fang Bo, Wang Y., Qi G. Phosphine‐Catalyzed Domino Annulation Reactions of o‐Aminotrifluoroacetophenone Derivatives with Morita−Baylis−Hillman Carbonates: Construction of Tetrahydrofuro[3,2‐b]indolines // Advanced Synthesis and Catalysis. 2024. Vol. 366. No. 10. pp. 2252-2256.
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TY - JOUR
DO - 10.1002/adsc.202400205
UR - https://onlinelibrary.wiley.com/doi/10.1002/adsc.202400205
TI - Phosphine‐Catalyzed Domino Annulation Reactions of o‐Aminotrifluoroacetophenone Derivatives with Morita−Baylis−Hillman Carbonates: Construction of Tetrahydrofuro[3,2‐b]indolines
T2 - Advanced Synthesis and Catalysis
AU - Zhu, Yannan
AU - Zhao, He
AU - Li, Qiuyun
AU - Fang Bo
AU - Wang, Yi-ning
AU - Qi, Gang
PY - 2024
DA - 2024/04/24
PB - Wiley
SP - 2252-2256
IS - 10
VL - 366
SN - 1615-4150
SN - 1615-4169
ER -
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@article{2024_Zhu,
author = {Yannan Zhu and He Zhao and Qiuyun Li and Fang Bo and Yi-ning Wang and Gang Qi},
title = {Phosphine‐Catalyzed Domino Annulation Reactions of o‐Aminotrifluoroacetophenone Derivatives with Morita−Baylis−Hillman Carbonates: Construction of Tetrahydrofuro[3,2‐b]indolines},
journal = {Advanced Synthesis and Catalysis},
year = {2024},
volume = {366},
publisher = {Wiley},
month = {apr},
url = {https://onlinelibrary.wiley.com/doi/10.1002/adsc.202400205},
number = {10},
pages = {2252--2256},
doi = {10.1002/adsc.202400205}
}
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MLA
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Zhu, Yannan, et al. “Phosphine‐Catalyzed Domino Annulation Reactions of o‐Aminotrifluoroacetophenone Derivatives with Morita−Baylis−Hillman Carbonates: Construction of Tetrahydrofuro[3,2‐b]indolines.” Advanced Synthesis and Catalysis, vol. 366, no. 10, Apr. 2024, pp. 2252-2256. https://onlinelibrary.wiley.com/doi/10.1002/adsc.202400205.