Wiley
Advanced Synthesis and Catalysis
,  volume 367 ,  issue 9 ,  publication number e202500080

Synthesis of Oxadendralenes by Thermal Oxy‐Cope Type Rearrangement of Bis(α‐hydroxyallenes)

Daniel San Martín 1
, 
Teresa Martínez del Campo 1
, 
Pedro Almendros 2
1
 
2
 
Instituto de Química Orgánica General IQOG, CSIC Juan de la Cierva 3 28006 Madrid Spain | 
Publication type: Journal Article
Publication date: 2025-03-12
Wiley
scimago Q1
wos Q1
SJR: 0.930
CiteScore: 8.0
Impact factor: 4.0
ISSN: 16154150, 16154169
Abstract

We report the direct and selective synthesis of oxadendralenes starting from readily available bis(α‐hydroxyallenes). The designed sequence involves a hitherto unknown oxy‐Cope rearrangement of allenols by supplying a site for the migration of the 1,2‐diene moiety. Moreover, the so‐prepared oxadendralenes were converted into valuable polyfunctionalized scaffolds through effective late‐stage diversification.

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San Martín D., Martínez del Campo T., Almendros P. Synthesis of Oxadendralenes by Thermal Oxy‐Cope Type Rearrangement of Bis(α‐hydroxyallenes) // Advanced Synthesis and Catalysis. 2025. Vol. 367. No. 9. e202500080
GOST all authors (up to 50) Copy
San Martín D., Martínez del Campo T., Almendros P. Synthesis of Oxadendralenes by Thermal Oxy‐Cope Type Rearrangement of Bis(α‐hydroxyallenes) // Advanced Synthesis and Catalysis. 2025. Vol. 367. No. 9. e202500080
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RIS Copy
TY - JOUR
DO - 10.1002/adsc.202500080
UR - https://advanced.onlinelibrary.wiley.com/doi/10.1002/adsc.202500080
TI - Synthesis of Oxadendralenes by Thermal Oxy‐Cope Type Rearrangement of Bis(α‐hydroxyallenes)
T2 - Advanced Synthesis and Catalysis
AU - San Martín, Daniel
AU - Martínez del Campo, Teresa
AU - Almendros, Pedro
PY - 2025
DA - 2025/03/12
PB - Wiley
IS - 9
VL - 367
SN - 1615-4150
SN - 1615-4169
ER -
BibTex
Cite this
BibTex (up to 50 authors) Copy
@article{2025_San Martín,
author = {Daniel San Martín and Teresa Martínez del Campo and Pedro Almendros},
title = {Synthesis of Oxadendralenes by Thermal Oxy‐Cope Type Rearrangement of Bis(α‐hydroxyallenes)},
journal = {Advanced Synthesis and Catalysis},
year = {2025},
volume = {367},
publisher = {Wiley},
month = {mar},
url = {https://advanced.onlinelibrary.wiley.com/doi/10.1002/adsc.202500080},
number = {9},
pages = {e202500080},
doi = {10.1002/adsc.202500080}
}