Angewandte Chemie, volume 135, issue 33

Circularly Polarized Luminescence from Cyclic (Alkyl)(Amino)Carbene Derived Propellers

Jan Lorkowski ^{1, 2}

Dylan Bouetard ²

Patrick Yorkgitis ¹

Milan Gembicky ¹

Thierry Roisnel ²

Nicolas Vanthuyne ³

D. Munz ⁴

Ludovic Favereau ⁵

Gilles Bertrand ¹

Marc Mauduit ²

Rodolphe Jazzar ¹

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UCSD–CNRS Joint Research Laboratory (UMI 3555) Department of Chemistry and Biochemistry University of California, San Diego La Jolla CA-92093-0343 USA |

Univ Rennes Ecole Nationale Supérieure de Chimie de Rennes, CNRS ISCR UMR 6226 35000 Rennes France

Aix Marseille Univ., CNRS, Centrale Marseille, ISM2 13013 Marseille France |

⁴

Coordination Chemistry Saarland University Campus C4.1 66123 Saarbrücken Germany |

⁵

Univ Rennes, CNRS ISCR - UMR 6226 35000 Rennes France |

Publication type: Journal Article

Publication date: 2023-07-10

Wiley

Journal: Angewandte Chemie

SJR: —

CiteScore: —

Impact factor: —

ISSN: 00448249, 15213757

DOI: 10.1002/ange.202305404

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General Medicine

Abstract

Organic circularly polarized luminescence (CPL)‐active molecular emitters featuring dynamic propeller‐like luminophores were prepared in one step from cyclic(alkyl)(amino) carbenes (CAACs). These molecules exhibit through‐space arene‐arene π‐delocalization and rapid intramolecular inter‐system crossing (ISC) in line with their helical character.

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Wiley

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Angewandte Chemie

SJR

—

CiteScore

—

Impact factor

—

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00448249 (Print)

15213757 (Electronic)

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Circularly Polarized Luminescence from Cyclic (Alkyl)(Amino)Carbene Derived Propellers

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