Wiley
Angewandte Chemie
,  том 136 ,  издание 3 ,  номер публикации e202316719

Lamellar Crystal Structure and Haldane Magnetism in NH4VPO4OH

Тип публикации: Journal Article
Дата публикации: 2023-12-14
Wiley
SJR: —
CiteScore: —
Impact factor: —
ISSN: 00448249, 15213757
General Medicine
Краткое описание

A novel vanadium hydroxide‐phosphate, NH4VPO4OH, was synthesized hydrothermally in V2O5−NH4H2PO4‐citric acid system at 230 °C. It was characterized by XRD, TG‐DSC, SEM‐EDX, FTIR and NMR spectroscopy. NH4VPO4OH is isostructural with NH4GaPO4OH and features edge‐sharing chains of VO6 octahedra. These chains running along [010] direction of the unit cell are connected by phosphate tetrahedra to form infinite layers parallel to the (100) plane. Ammonium cations are embedded between the heteropolyhedral layers. According to the thermodynamic and NMR measurements supported by the first‐principles calculations, NH4VPO4OH presents a rare case of Haldane spin system with spin S=1 based on V3+ ions.

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Samarin A. S. et al. Lamellar Crystal Structure and Haldane Magnetism in NH4VPO4OH // Angewandte Chemie. 2023. Vol. 136. No. 3. e202316719
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Samarin A. S., Trussov I. A., Pchelkina Z. V., Fedotov S. S., Ovchenkov Y. A., Zhurenko S. V., Tkachev A. V., Gippius A. A., Shvanskaya L. V., Vasiliev A. N. Lamellar Crystal Structure and Haldane Magnetism in NH4VPO4OH // Angewandte Chemie. 2023. Vol. 136. No. 3. e202316719
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TY - JOUR
DO - 10.1002/ange.202316719
UR - https://onlinelibrary.wiley.com/doi/10.1002/ange.202316719
TI - Lamellar Crystal Structure and Haldane Magnetism in NH4VPO4OH
T2 - Angewandte Chemie
AU - Samarin, Aleksandr Sh.
AU - Trussov, Ivan A
AU - Pchelkina, Zlata V.
AU - Fedotov, Stanislav S.
AU - Ovchenkov, Yevgeniy A.
AU - Zhurenko, Sergei V
AU - Tkachev, Alexei V.
AU - Gippius, Andrei A
AU - Shvanskaya, Larisa V.
AU - Vasiliev, A. N.
PY - 2023
DA - 2023/12/14
PB - Wiley
IS - 3
VL - 136
SN - 0044-8249
SN - 1521-3757
ER -
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@article{2023_Samarin,
author = {Aleksandr Sh. Samarin and Ivan A Trussov and Zlata V. Pchelkina and Stanislav S. Fedotov and Yevgeniy A. Ovchenkov and Sergei V Zhurenko and Alexei V. Tkachev and Andrei A Gippius and Larisa V. Shvanskaya and A. N. Vasiliev},
title = {Lamellar Crystal Structure and Haldane Magnetism in NH4VPO4OH},
journal = {Angewandte Chemie},
year = {2023},
volume = {136},
publisher = {Wiley},
month = {dec},
url = {https://onlinelibrary.wiley.com/doi/10.1002/ange.202316719},
number = {3},
pages = {e202316719},
doi = {10.1002/ange.202316719}
}