Orotate complexes. Synthesis and crystal structure of lithium orotate(—I) monohydrate and magnesium bis[ orotate(—I)] octahydrate
Publication type: Journal Article
Publication date: 1990-12-01
Inorganic Chemistry
Abstract
Neutralization of orotic acid (OrH2) by lithium or magnesium hydroxide in aqueous medium yields the crystalline metal orotate hydrates Li(OrH). H2O (1) and Mg(OrH)2. (H2O)6 (2). By single-crystal X-ray diffraction studies it has been shown that 1 (space group P1) forms a layer structure, with lithium in a tetrahedral environment of oxygen atoms from three different orotate( - I) anions (one carboxylate and two uracil oxygen atoms) and the water molecule. 2 (space group P21/c) has been shown to feature a hexaquo complex of magnesium, the Mg(H2O)26 cations being associated with two hydrated OrH⊖ ions only through hydrogen bonds. The anions are also engaged in “base-pairing” hydrogen bonds between the planar uracil ring systems of different units. The results are relevant for applications of magnesium orotates in magnesium therapy.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
2
3
4
5
|
|
|
Polyhedron
5 publications, 10.42%
|
|
|
Inorganic Chemistry Communication
3 publications, 6.25%
|
|
|
Journal of Molecular Structure
3 publications, 6.25%
|
|
|
Applied Organometallic Chemistry
3 publications, 6.25%
|
|
|
CrystEngComm
3 publications, 6.25%
|
|
|
Inorganic Chemistry
2 publications, 4.17%
|
|
|
Journal of Inorganic Biochemistry
2 publications, 4.17%
|
|
|
Molecules
2 publications, 4.17%
|
|
|
Chemische Berichte
2 publications, 4.17%
|
|
|
Journal of Physical Chemistry B
1 publication, 2.08%
|
|
|
Canadian Journal of Chemistry
1 publication, 2.08%
|
|
|
Acta Crystallographica Section E: Crystallographic Communications
1 publication, 2.08%
|
|
|
European Journal of Mass Spectrometry
1 publication, 2.08%
|
|
|
Journal of Chemical Crystallography
1 publication, 2.08%
|
|
|
Journal of Molecular Structure THEOCHEM
1 publication, 2.08%
|
|
|
Vibrational Spectroscopy
1 publication, 2.08%
|
|
|
Journal of Solid State Chemistry
1 publication, 2.08%
|
|
|
Journal of Genetics and Genomics
1 publication, 2.08%
|
|
|
Biochimica et Biophysica Acta - Bioenergetics
1 publication, 2.08%
|
|
|
Journal of Organometallic Chemistry
1 publication, 2.08%
|
|
|
European Journal of Medicinal Chemistry
1 publication, 2.08%
|
|
|
Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
1 publication, 2.08%
|
|
|
Chemical Physics
1 publication, 2.08%
|
|
|
Biopolymers
1 publication, 2.08%
|
|
|
European Journal of Inorganic Chemistry
1 publication, 2.08%
|
|
|
Archiv der Pharmazie
1 publication, 2.08%
|
|
|
Zeitschrift fur Anorganische und Allgemeine Chemie
1 publication, 2.08%
|
|
|
Crystal Growth and Design
1 publication, 2.08%
|
|
|
ACS Omega
1 publication, 2.08%
|
|
|
Journal of the Chemical Society Dalton Transactions
1 publication, 2.08%
|
|
|
1
2
3
4
5
|
Publishers
|
5
10
15
20
25
|
|
|
Elsevier
23 publications, 47.92%
|
|
|
Wiley
9 publications, 18.75%
|
|
|
American Chemical Society (ACS)
5 publications, 10.42%
|
|
|
Royal Society of Chemistry (RSC)
4 publications, 8.33%
|
|
|
MDPI
2 publications, 4.17%
|
|
|
Canadian Science Publishing
1 publication, 2.08%
|
|
|
International Union of Crystallography (IUCr)
1 publication, 2.08%
|
|
|
SAGE
1 publication, 2.08%
|
|
|
Springer Nature
1 publication, 2.08%
|
|
|
Walter de Gruyter
1 publication, 2.08%
|
|
|
5
10
15
20
25
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
48
Total citations:
48
Citations from 2024:
1
(2.08%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Bach I., Kumberger O., Schmidbaur H. Orotate complexes. Synthesis and crystal structure of lithium orotate(—I) monohydrate and magnesium bis[ orotate(—I)] octahydrate // Chemische Berichte. 1990. Vol. 123. No. 12. pp. 2267-2271.
GOST all authors (up to 50)
Copy
Bach I., Kumberger O., Schmidbaur H. Orotate complexes. Synthesis and crystal structure of lithium orotate(—I) monohydrate and magnesium bis[ orotate(—I)] octahydrate // Chemische Berichte. 1990. Vol. 123. No. 12. pp. 2267-2271.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/cber.19901231207
UR - https://doi.org/10.1002/cber.19901231207
TI - Orotate complexes. Synthesis and crystal structure of lithium orotate(—I) monohydrate and magnesium bis[ orotate(—I)] octahydrate
T2 - Chemische Berichte
AU - Bach, Ina
AU - Kumberger, Otto
AU - Schmidbaur, H.
PY - 1990
DA - 1990/12/01
PB - Wiley
SP - 2267-2271
IS - 12
VL - 123
SN - 0009-2940
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1990_Bach,
author = {Ina Bach and Otto Kumberger and H. Schmidbaur},
title = {Orotate complexes. Synthesis and crystal structure of lithium orotate(—I) monohydrate and magnesium bis[ orotate(—I)] octahydrate},
journal = {Chemische Berichte},
year = {1990},
volume = {123},
publisher = {Wiley},
month = {dec},
url = {https://doi.org/10.1002/cber.19901231207},
number = {12},
pages = {2267--2271},
doi = {10.1002/cber.19901231207}
}
Cite this
MLA
Copy
Bach, Ina, et al. “Orotate complexes. Synthesis and crystal structure of lithium orotate(—I) monohydrate and magnesium bis[ orotate(—I)] octahydrate.” Chemische Berichte, vol. 123, no. 12, Dec. 1990, pp. 2267-2271. https://doi.org/10.1002/cber.19901231207.