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Chemistry - A European Journal
,  том 20 ,  издание 18 ,  страницы 5380-5387

Magnetic Coupling and Optical Properties of theS6-Dodecakis(trifluoromethyl)fullerene Radical Anions in the Layered Salt (PPN+)[C60(CF3)12.−]

Тип публикации: Journal Article
Дата публикации: 2014-03-26
Wiley
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CiteScore: 5.8
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ISSN: 09476539, 15213765
General Chemistry
Catalysis
Organic Chemistry
Краткое описание
Anionic fullerenes: A salt of a multiply derivatized fullerene anion, namely, (PPN+)[C60(CF3)12.−] (1; PPN+=bis(triphenylphosphine)iminium), was obtained as single crystals (see figure; C gray, F green). The crystals of 1 exhibit a narrow EPR signal and rather strong antiferromagnetic coupling between the spins of the C60(CF3)12.− radical anions. It was assumed that this coupling is mediated by the network of short F⋅⋅⋅F contacts in the layers of radical anions.
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Konarev D. V. et al. Magnetic Coupling and Optical Properties of theS6-Dodecakis(trifluoromethyl)fullerene Radical Anions in the Layered Salt (PPN+)[C60(CF3)12.−] // Chemistry - A European Journal. 2014. Vol. 20. No. 18. pp. 5380-5387.
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Konarev D. V., Romanova N. A., Panin R. A., Goryunkov A., Troyanov S., Lyubovskaya R. N. Magnetic Coupling and Optical Properties of theS6-Dodecakis(trifluoromethyl)fullerene Radical Anions in the Layered Salt (PPN+)[C60(CF3)12.−] // Chemistry - A European Journal. 2014. Vol. 20. No. 18. pp. 5380-5387.
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TY - JOUR
DO - 10.1002/chem.201304850
UR - https://doi.org/10.1002/chem.201304850
TI - Magnetic Coupling and Optical Properties of theS6-Dodecakis(trifluoromethyl)fullerene Radical Anions in the Layered Salt (PPN+)[C60(CF3)12.−]
T2 - Chemistry - A European Journal
AU - Konarev, Dmitri V.
AU - Romanova, Natalia A
AU - Panin, Roman A
AU - Goryunkov, A.
AU - Troyanov, Sergey
AU - Lyubovskaya, Rimma N.
PY - 2014
DA - 2014/03/26
PB - Wiley
SP - 5380-5387
IS - 18
VL - 20
PMID - 24668622
SN - 0947-6539
SN - 1521-3765
ER -
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@article{2014_Konarev,
author = {Dmitri V. Konarev and Natalia A Romanova and Roman A Panin and A. Goryunkov and Sergey Troyanov and Rimma N. Lyubovskaya},
title = {Magnetic Coupling and Optical Properties of theS6-Dodecakis(trifluoromethyl)fullerene Radical Anions in the Layered Salt (PPN+)[C60(CF3)12.−]},
journal = {Chemistry - A European Journal},
year = {2014},
volume = {20},
publisher = {Wiley},
month = {mar},
url = {https://doi.org/10.1002/chem.201304850},
number = {18},
pages = {5380--5387},
doi = {10.1002/chem.201304850}
}
MLA
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Konarev, Dmitri V., et al. “Magnetic Coupling and Optical Properties of theS6-Dodecakis(trifluoromethyl)fullerene Radical Anions in the Layered Salt (PPN+)[C60(CF3)12.−].” Chemistry - A European Journal, vol. 20, no. 18, Mar. 2014, pp. 5380-5387. https://doi.org/10.1002/chem.201304850.
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