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Oxoanionic Noble Metal Compounds from Fuming Nitric Acid: The Palladium Examples Pd(NO3)2and Pd(CH3SO3)2

Jörn Bruns
Thorsten Klüner
Mathias S Wickleder
Тип публикацииJournal Article
Дата публикации2014-11-27
scimago Q1
wos Q2
БС1
SJR0.981
CiteScore6.7
Impact factor3.7
ISSN09476539, 15213765
General Chemistry
Catalysis
Organic Chemistry
Краткое описание
The oxidation of elemental palladium at 100 °C in a mixture of fuming nitric acid and a pyridine-SO3 complex leads to the anhydrous nitrate Pd(NO3)2 (monoclinic, P2(1)/n, Z=2, a=469.12(3) pm, b=593.89(3) pm, c=805.72(4) pm, β=105.989(3)°, V=215.79(2) Å(3)). The Pd(2+) ions are in square-planar coordination with four monodentate nitrate groups which are connected to further palladium atoms, leading to a layer structure. The reaction of elemental palladium with a mixture of fuming nitric acid and methanesulfonic acid at 120 °C leads to single crystals of Pd(CH3SO3)2 (monoclinic, P2(1)/n, Z=2, a=480.44(1) pm, b=1085.53(3) pm, c=739.78(2) pm, β=102.785(1)°, V=376.254(17) Å(3)). Also in this structure the Pd(2+) ions are in square-planar coordination with four monodentate anions; however, the connection to adjacent palladium atoms leads to a chain-type structure. The thermal decomposition of the compounds has been investigated by means of DSC/TG measurements. Furthermore, IR and Raman spectra have been recorded, and an assignment of the observed vibrational frequencies has been carried out based on theoretical investigations.
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Bruns J., Klüner T., Wickleder M. S. Oxoanionic Noble Metal Compounds from Fuming Nitric Acid: The Palladium Examples Pd(NO3)2and Pd(CH3SO3)2 // Chemistry - A European Journal. 2014. Vol. 21. No. 3. pp. 1294-1301.
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Bruns J., Klüner T., Wickleder M. S. Oxoanionic Noble Metal Compounds from Fuming Nitric Acid: The Palladium Examples Pd(NO3)2and Pd(CH3SO3)2 // Chemistry - A European Journal. 2014. Vol. 21. No. 3. pp. 1294-1301.
RIS |
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TY - JOUR
DO - 10.1002/chem.201405355
UR - https://doi.org/10.1002/chem.201405355
TI - Oxoanionic Noble Metal Compounds from Fuming Nitric Acid: The Palladium Examples Pd(NO3)2and Pd(CH3SO3)2
T2 - Chemistry - A European Journal
AU - Bruns, Jörn
AU - Klüner, Thorsten
AU - Wickleder, Mathias S
PY - 2014
DA - 2014/11/27
PB - Wiley
SP - 1294-1301
IS - 3
VL - 21
PMID - 25431333
SN - 0947-6539
SN - 1521-3765
ER -
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@article{2014_Bruns,
author = {Jörn Bruns and Thorsten Klüner and Mathias S Wickleder},
title = {Oxoanionic Noble Metal Compounds from Fuming Nitric Acid: The Palladium Examples Pd(NO3)2and Pd(CH3SO3)2},
journal = {Chemistry - A European Journal},
year = {2014},
volume = {21},
publisher = {Wiley},
month = {nov},
url = {https://doi.org/10.1002/chem.201405355},
number = {3},
pages = {1294--1301},
doi = {10.1002/chem.201405355}
}
MLA
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Bruns, Jörn, et al. “Oxoanionic Noble Metal Compounds from Fuming Nitric Acid: The Palladium Examples Pd(NO3)2and Pd(CH3SO3)2.” Chemistry - A European Journal, vol. 21, no. 3, Nov. 2014, pp. 1294-1301. https://doi.org/10.1002/chem.201405355.