Chemistry - A European Journal, volume 22, issue 33, pages 11597-11600

A Short Synthesis of Aphanamol I in Both Racemic and Enantiopure Forms

Steven J Ferrara ¹

Jonathan W Burton ¹

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Department of Chemistry; University of Oxford; Chemistry Research Laboratory; Mansfield Road Oxford OX1 3TA UK |

Publication type: Journal Article

Publication date: 2016-07-08

Wiley

Journal: Chemistry - A European Journal

scimago Q1

SJR: 1.058

CiteScore: 7.9

Impact factor: 3.9

ISSN: 09476539, 15213765

DOI: 10.1002/chem.201602669

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PubMed ID: 27389970

General Chemistry

Catalysis

Organic Chemistry

Abstract

A short synthesis of the biologically active sesquiterpene natural product (+)-aphanamol I in both racemic and enantiopure forms is reported. Key steps include: a catalytic enantioselective conjugate addition, an oxidative radical cyclization, and a ring-expanding Claisen rearrangement.

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Publisher

Wiley

Journal

Chemistry - A European Journal

scimago Q1

SJR

1.058

CiteScore

7.9

Impact factor

3.9

ISSN

09476539 (Print)

15213765 (Electronic)

A Short Synthesis of Aphanamol I in Both Racemic and Enantiopure Forms

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