1‐(Azidomethyl)‐5 H ‐Tetrazole: A Powerful New Ligand for Highly Energetic Coordination Compounds
Publication type: Journal Article
Publication date: 2022-05-25
scimago Q1
wos Q2
SJR: 0.981
CiteScore: 6.7
Impact factor: 3.7
ISSN: 09476539, 15213765
PubMed ID:
35502815
General Chemistry
Catalysis
Organic Chemistry
Abstract
Shortening the alkyl chain in 1-(Azidoethyl)-5H-tetrazole (AET) to a methylene bridge results in the formation of highly sensitive 1-(azidomethyl)-5H-tetrazole (AzMT), which exhibits a greatly increased enthalpy of formation, hence a drastically increased detonation performance is calculated. Like AET, AzMT can be applied as ligand in the energetic coordination compounds (ECC) of several transition metals, showing the characteristics of primary explosives capable of initiating pentaerythritol tetranitrate. The ligand as well as all ECCs are fully characterized.
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24
Total citations:
24
Citations from 2024:
9
(37.5%)
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GOST
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Kofen M. et al. 1‐(Azidomethyl)‐5 H ‐Tetrazole: A Powerful New Ligand for Highly Energetic Coordination Compounds // Chemistry - A European Journal. 2022. Vol. 28. No. 38.
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Kofen M., Lommel M., Wurzenberger M. H. H., Klapötke T. M., Stierstorfer J. 1‐(Azidomethyl)‐5 H ‐Tetrazole: A Powerful New Ligand for Highly Energetic Coordination Compounds // Chemistry - A European Journal. 2022. Vol. 28. No. 38.
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RIS
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TY - JOUR
DO - 10.1002/chem.202200492
UR - https://doi.org/10.1002/chem.202200492
TI - 1‐(Azidomethyl)‐5 H ‐Tetrazole: A Powerful New Ligand for Highly Energetic Coordination Compounds
T2 - Chemistry - A European Journal
AU - Kofen, Moritz
AU - Lommel, Marcus
AU - Wurzenberger, Maximilian H H
AU - Klapötke, Thomas M.
AU - Stierstorfer, Jörg
PY - 2022
DA - 2022/05/25
PB - Wiley
IS - 38
VL - 28
PMID - 35502815
SN - 0947-6539
SN - 1521-3765
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2022_Kofen,
author = {Moritz Kofen and Marcus Lommel and Maximilian H H Wurzenberger and Thomas M. Klapötke and Jörg Stierstorfer},
title = {1‐(Azidomethyl)‐5 H ‐Tetrazole: A Powerful New Ligand for Highly Energetic Coordination Compounds},
journal = {Chemistry - A European Journal},
year = {2022},
volume = {28},
publisher = {Wiley},
month = {may},
url = {https://doi.org/10.1002/chem.202200492},
number = {38},
doi = {10.1002/chem.202200492}
}