The Reaction of Methyl Isoferulate with FeCl3 or Ag2O—Hypothesis on the Biosynthesis of Lithospermic Acids and Related Nor and Neolignans.
Publication type: Journal Article
Publication date: 2003-08-05
General Medicine
Abstract
Methyl isoferulate reacts with FeCl 3 to give (2-6) dimer 3 (6-6) dimer 4 and (6-O-3) dimer 5 in low yields, whereas it reacts with Ag 2 O leading to (2-O-3) dimer 6 and (6-O-3, 2-O-3) trimer 7 . By comparison with literature data, we suggest that the biosynthesis of lithospermic acids and related nor and neolignans that possess a β-2 bond may be due to the cross dimerisation of ferulate radical on isoferulate.
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Cotelle P., Vezin H. The Reaction of Methyl Isoferulate with FeCl3 or Ag2O—Hypothesis on the Biosynthesis of Lithospermic Acids and Related Nor and Neolignans. // ChemInform. 2003. Vol. 34. No. 31.
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Cotelle P., Vezin H. The Reaction of Methyl Isoferulate with FeCl3 or Ag2O—Hypothesis on the Biosynthesis of Lithospermic Acids and Related Nor and Neolignans. // ChemInform. 2003. Vol. 34. No. 31.
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TY - JOUR
DO - 10.1002/chin.200331234
UR - https://doi.org/10.1002/chin.200331234
TI - The Reaction of Methyl Isoferulate with FeCl3 or Ag2O—Hypothesis on the Biosynthesis of Lithospermic Acids and Related Nor and Neolignans.
T2 - ChemInform
AU - Cotelle, Philippe
AU - Vezin, Hervé
PY - 2003
DA - 2003/08/05
PB - Wiley
IS - 31
VL - 34
SN - 0931-7597
SN - 1522-2667
ER -
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@article{2003_Cotelle,
author = {Philippe Cotelle and Hervé Vezin},
title = {The Reaction of Methyl Isoferulate with FeCl3 or Ag2O—Hypothesis on the Biosynthesis of Lithospermic Acids and Related Nor and Neolignans.},
journal = {ChemInform},
year = {2003},
volume = {34},
publisher = {Wiley},
month = {aug},
url = {https://doi.org/10.1002/chin.200331234},
number = {31},
doi = {10.1002/chin.200331234}
}