ChemPhysChem, volume 24, issue 17

Memristive Effect in Ti3C2Tx(MXene) Polyelectrolyte Multilayers

Aglikov Aleksandr ¹

Volkova Olga ¹

Bondar Anna ¹

Moskalenko Ivan ¹

Novikov Alexander ¹

Skorb Ekaterina V ¹

Smirnov Evgeny A. ¹

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Infochemistry Scientific Center ITMO University Lomonosova str. 9 Saint Petersburg 191002 Russian Federation |

Publication type: Journal Article

Publication date: 2023-07-17

Wiley

Journal: ChemPhysChem

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Impact factor: 2.9

ISSN: 14394235, 14397641

DOI: 10.1002/cphc.202300187

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Physical and Theoretical Chemistry

Atomic and Molecular Physics, and Optics

Abstract

The emerging novel class of two‐dimensional materials – MХenes – have attracted significant research attention. However, there are only few reports on using the most prominent member of the MXene family, Ti₃C₂T_x, as an active material for memristive devices within a polyelectrolyte matrix and its deposition on inert electrodes like ITO and Pt. In this study, we systematically investigate Ti₃C₂T_x MXenes synthesized with two classical delamination agents, such as lithium chloride and tetramethylammonium hydroxide, to identify the most suitable candidate for memristive device applications. The characteristics of memristors based on the hybrid structures consisting of MXene−polyelectrolyte multilayers, specifically polyethyleneimine (PEI) and poly(sodium 4‐styrenesulfonate) (PSS) are explored. The PEI(MXene)/PSS memristor exhibits a voltage threshold (V_SET/RESET) range of 1.5–2.0 V, enabling the transition from a high‐resistive state (HRS) to a low‐resistive state (LRS), along with a significant current switching ratio of approximately two orders of magnitude. The observed V_SET/RESET difference of approximately 4 V is further supported by density functional theory (DFT) calculated redox potential. These findings underscore the potential of polyelectrolyte‐based memristors, such as the in PEI−Ti₃C₂T_x−PSS system, in facilitating the development of highly functional, self‐assembled memristive devices with diverse applications.

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ACS Applied Electronic Materials	ACS Applied Electronic Materials, 1, 33.33% ACS Applied Electronic Materials 1 publication, 33.33%
Materials Advances	Materials Advances, 1, 33.33% Materials Advances 1 publication, 33.33%
ACS Applied Nano Materials	ACS Applied Nano Materials, 1, 33.33% ACS Applied Nano Materials 1 publication, 33.33%
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American Chemical Society (ACS)	American Chemical Society (ACS), 2, 66.67% American Chemical Society (ACS) 2 publications, 66.67%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 1, 33.33% Royal Society of Chemistry (RSC) 1 publication, 33.33%
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Aglikov A. et al. Memristive Effect in Ti3C2Tx(MXene) Polyelectrolyte Multilayers // ChemPhysChem. 2023. Vol. 24. No. 17.

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Aglikov A., Volkova O., Bondar A., Moskalenko I., Novikov A., Skorb E. V., Smirnov E. A. Memristive Effect in Ti3C2Tx(MXene) Polyelectrolyte Multilayers // ChemPhysChem. 2023. Vol. 24. No. 17.

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TY - JOUR

DO - 10.1002/cphc.202300187

UR - https://doi.org/10.1002%2Fcphc.202300187

TI - Memristive Effect in Ti3C2Tx(MXene) Polyelectrolyte Multilayers

T2 - ChemPhysChem

AU - Aglikov, Aleksandr

AU - Volkova, Olga

AU - Bondar, Anna

AU - Moskalenko, Ivan

AU - Novikov, Alexander

AU - Skorb, Ekaterina V

AU - Smirnov, Evgeny A.

PY - 2023

DA - 2023/07/17 00:00:00

PB - Wiley

IS - 17

VL - 24

SN - 1439-4235

SN - 1439-7641

ER -

BibTex

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BibTex Copy

@article{2023_Aglikov,

author = {Aleksandr Aglikov and Olga Volkova and Anna Bondar and Ivan Moskalenko and Alexander Novikov and Ekaterina V Skorb and Evgeny A. Smirnov},

title = {Memristive Effect in Ti3C2Tx(MXene) Polyelectrolyte Multilayers},

journal = {ChemPhysChem},

year = {2023},

volume = {24},

publisher = {Wiley},

month = {jul},

url = {https://doi.org/10.1002%2Fcphc.202300187},

number = {17},

doi = {10.1002/cphc.202300187}

}

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Publisher

Wiley

Journal

ChemPhysChem

Quartile SCImago

Quartile WOS

Impact factor

2.9

ISSN

14394235 (Print)
14397641 (Electronic)

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