Rhodium and Iridium Complexes with α‐Diketimine Ligands: Oxidative Addition of H 2 and O 2
Publication type: Journal Article
Publication date: 2011-04-21
scimago Q2
wos Q3
SJR: 0.459
CiteScore: 3.9
Impact factor: 2.0
ISSN: 14341948, 10990682
Inorganic Chemistry
Abstract
The treatment of [M(μ-Cl)(coe)2]2 (M = Rh, Ir; coe = cyclooctene) with the α-diketimines ArN=C(Me)C(Me)=NAr (Ar = Ph, Xy; Xy = 2,6-Me2C6H3) in thf, followed by the addition of CNtBu, gave the α-diketimine complexes [M(Cl){ArN=C(Me)C(Me)=NAr} (CNtBu)] (1: M = Rh, Ar = Ph; 2: M = Rh, Ar = Xy; 3: M = Ir, Ar = Xy). The reaction of 3 with dihydrogen resulted in the formation of the iridium dihydrido complex [Ir(Cl)(H)2{XyN=C(Me)C(Me)=NXy}(CNtBu)] (4). The complexes 2 and 3 reacted with O2 or 18O2 to yield the peroxido complexes [M(Cl)(O2){XyN=C(Me)C(Me)=NXy}(CNtBu)] (5a: M = Rh; 6a: M = Ir) and [M(Cl)(18O2){XyN=C(Me)C(Me)=NXy}(CNtBu)] (5b: M = Rh; 6b: M = Ir), respectively. All of the complexes were characterized by NMR and IR spectroscopy. In addition, complexes 3 and 5a were characterized by X-ray crystallography.
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Penner A., Braun T. Rhodium and Iridium Complexes with α‐Diketimine Ligands: Oxidative Addition of H 2 and O 2 // European Journal of Inorganic Chemistry. 2011. Vol. 2011. No. 16. pp. 2579-2587.
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Penner A., Braun T. Rhodium and Iridium Complexes with α‐Diketimine Ligands: Oxidative Addition of H 2 and O 2 // European Journal of Inorganic Chemistry. 2011. Vol. 2011. No. 16. pp. 2579-2587.
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TY - JOUR
DO - 10.1002/ejic.201100135
UR - https://doi.org/10.1002/ejic.201100135
TI - Rhodium and Iridium Complexes with α‐Diketimine Ligands: Oxidative Addition of H 2 and O 2
T2 - European Journal of Inorganic Chemistry
AU - Penner, Anna
AU - Braun, Thomas
PY - 2011
DA - 2011/04/21
PB - Wiley
SP - 2579-2587
IS - 16
VL - 2011
SN - 1434-1948
SN - 1099-0682
ER -
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BibTex (up to 50 authors)
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@article{2011_Penner,
author = {Anna Penner and Thomas Braun},
title = {Rhodium and Iridium Complexes with α‐Diketimine Ligands: Oxidative Addition of H 2 and O 2},
journal = {European Journal of Inorganic Chemistry},
year = {2011},
volume = {2011},
publisher = {Wiley},
month = {apr},
url = {https://doi.org/10.1002/ejic.201100135},
number = {16},
pages = {2579--2587},
doi = {10.1002/ejic.201100135}
}
Cite this
MLA
Copy
Penner, Anna, and Thomas Braun. “Rhodium and Iridium Complexes with α‐Diketimine Ligands: Oxidative Addition of H 2 and O 2.” European Journal of Inorganic Chemistry, vol. 2011, no. 16, Apr. 2011, pp. 2579-2587. https://doi.org/10.1002/ejic.201100135.