Solvent and Dihalide Substituent Effects on Crystal Structure, Spin‐Crossover Behavior and Conductivity of the Cationic Mn(III) Complexes with Electroactive TCNQ Counteranions
Aleksandra V Tiunova
1, 2
,
A. V. Kazakova
1
,
Gennady V Shilov
1
,
Lev I Buravov
1
,
Aleksei I Dmitriev
1
,
Mikhail V Zhidkov
1
,
Vladimir N Zverev
3
,
Eduard B. Yagubskii
1
,
Sergei M. Aldoshin
1
Publication type: Journal Article
Publication date: 2024-05-29
scimago Q2
wos Q3
SJR: 0.459
CiteScore: 3.9
Impact factor: 2.0
ISSN: 14341948, 10990682
Inorganic Chemistry
Abstract
Cationic Mn(III) complexes with 3,5‐Hal‐sal2323 (Hal=diCl, diBr, BrCl) ligands containing electroactive TCNQ anions as counterions have been synthesized: [Mn(3,5‐diCl‐sal2323)](TCNQ)2 (1), [Mn(3,5‐diBr‐sal2323)]2(TCNQ)3⋅6CH3CN (2), and [Mn(3,5‐Br,Cl‐sal2323)]2(TCNQ)3⋅6CH3CN (3). The crystal structures, magnetic and conducting properties of the obtained compounds have been investigated. In 1, an incomplete spin transition from the low‐spin (LS) state at 100 K to the high‐spin (HS) state upon heating to 400 K is observed. Isostructural complexes 2 and 3 contain 6 molecules of solvated acetonitrile, which is lost upon heating, accompanied by the crystal structure transformation. As a result, desolvated complexes jump to the HS state. The temperature dependences of resistivity 2 and 3 show resistivity jumps associated with the loss of lattice solvent.
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Citations from 2024:
4
(100%)
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Tiunova A. V. et al. Solvent and Dihalide Substituent Effects on Crystal Structure, Spin‐Crossover Behavior and Conductivity of the Cationic Mn(III) Complexes with Electroactive TCNQ Counteranions // European Journal of Inorganic Chemistry. 2024. Vol. 27. No. 18. e202300749
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Tiunova A. V., Korchagin D. V., Kazakova A. V., Shilov G. V., Buravov L. I., Dmitriev A. I., Zhidkov M. V., Zverev V. N., Yagubskii E. B., Aldoshin S. M. Solvent and Dihalide Substituent Effects on Crystal Structure, Spin‐Crossover Behavior and Conductivity of the Cationic Mn(III) Complexes with Electroactive TCNQ Counteranions // European Journal of Inorganic Chemistry. 2024. Vol. 27. No. 18. e202300749
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TY - JOUR
DO - 10.1002/ejic.202300749
UR - https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.202300749
TI - Solvent and Dihalide Substituent Effects on Crystal Structure, Spin‐Crossover Behavior and Conductivity of the Cationic Mn(III) Complexes with Electroactive TCNQ Counteranions
T2 - European Journal of Inorganic Chemistry
AU - Tiunova, Aleksandra V
AU - Korchagin, Denis V
AU - Kazakova, A. V.
AU - Shilov, Gennady V
AU - Buravov, Lev I
AU - Dmitriev, Aleksei I
AU - Zhidkov, Mikhail V
AU - Zverev, Vladimir N
AU - Yagubskii, Eduard B.
AU - Aldoshin, Sergei M.
PY - 2024
DA - 2024/05/29
PB - Wiley
IS - 18
VL - 27
SN - 1434-1948
SN - 1099-0682
ER -
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@article{2024_Tiunova,
author = {Aleksandra V Tiunova and Denis V Korchagin and A. V. Kazakova and Gennady V Shilov and Lev I Buravov and Aleksei I Dmitriev and Mikhail V Zhidkov and Vladimir N Zverev and Eduard B. Yagubskii and Sergei M. Aldoshin},
title = {Solvent and Dihalide Substituent Effects on Crystal Structure, Spin‐Crossover Behavior and Conductivity of the Cationic Mn(III) Complexes with Electroactive TCNQ Counteranions},
journal = {European Journal of Inorganic Chemistry},
year = {2024},
volume = {27},
publisher = {Wiley},
month = {may},
url = {https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.202300749},
number = {18},
pages = {e202300749},
doi = {10.1002/ejic.202300749}
}