Stepwise catalytic transformations of renewable feedstock arising from plant oils
Publication type: Journal Article
Publication date: 2013-02-01
scimago Q2
wos Q3
SJR: 0.430
CiteScore: 4.0
Impact factor: 1.8
ISSN: 14387697, 14389312
General Chemistry
Biotechnology
Industrial and Manufacturing Engineering
Food Science
Abstract
Two synthetic approaches to produce functionalized plant oil derivatives were investigated. The ruthenium-catalyzed ene-yne cross-metathesis of propargylic carbonates with terminal olefins arising from ethenolysis of methyl oleate provides conjugated dienes. It was shown that the reactivity of these dienes in Diels–Alder [4 + 2]-cycloaddition with symmetrical electron-deficient alkynes towards the formation of cyclohexadienes was effective but limited by stereochemical considerations. On the other hand, the stepwise ene-yne cross-metathesis followed by ruthenium-catalyzed nucleophilic allylic substitution by O, N, and C-nucleophiles was very efficient both in term of reactivity and regioselectivity.
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GOST
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Dupé A. et al. Stepwise catalytic transformations of renewable feedstock arising from plant oils // European Journal of Lipid Science and Technology. 2013. Vol. 115. No. 5. pp. 490-500.
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Dupé A., Le Ravalec V., Fischmeister C., Bruneau C. Stepwise catalytic transformations of renewable feedstock arising from plant oils // European Journal of Lipid Science and Technology. 2013. Vol. 115. No. 5. pp. 490-500.
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RIS
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TY - JOUR
DO - 10.1002/ejlt.201200364
UR - https://doi.org/10.1002/ejlt.201200364
TI - Stepwise catalytic transformations of renewable feedstock arising from plant oils
T2 - European Journal of Lipid Science and Technology
AU - Dupé, Antoine
AU - Le Ravalec, Virginie
AU - Fischmeister, C.
AU - Bruneau, Christian
PY - 2013
DA - 2013/02/01
PB - Wiley
SP - 490-500
IS - 5
VL - 115
SN - 1438-7697
SN - 1438-9312
ER -
Cite this
BibTex (up to 50 authors)
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@article{2013_Dupé,
author = {Antoine Dupé and Virginie Le Ravalec and C. Fischmeister and Christian Bruneau},
title = {Stepwise catalytic transformations of renewable feedstock arising from plant oils},
journal = {European Journal of Lipid Science and Technology},
year = {2013},
volume = {115},
publisher = {Wiley},
month = {feb},
url = {https://doi.org/10.1002/ejlt.201200364},
number = {5},
pages = {490--500},
doi = {10.1002/ejlt.201200364}
}
Cite this
MLA
Copy
Dupé, Antoine, et al. “Stepwise catalytic transformations of renewable feedstock arising from plant oils.” European Journal of Lipid Science and Technology, vol. 115, no. 5, Feb. 2013, pp. 490-500. https://doi.org/10.1002/ejlt.201200364.