volume 2012 issue 3 pages 587-594

LDA-Mediated Cascade Carbolithiation Reactions of Vinylidenecyclopropanes with Enones and N-Sulfonated Imines as well as Nitroalkene and (Phenylmethylidene)malononitrile

Publication typeJournal Article
Publication date2011-11-28
scimago Q2
wos Q2
SJR0.558
CiteScore4.3
Impact factor2.7
ISSN1434193X, 10990690
Organic Chemistry
Physical and Theoretical Chemistry
Abstract
LDA-mediated cascade carbolithiation reactions of vinylidenecyclopropanes with enones and N-sulfonated imines as well as nitroalkene and (phenylmethylidene)malononitrile in THF at –78 °C have been realized; the corresponding novel adducts were produced in moderate to good yields with moderate to high diastereoselectivities. The scope and limitations are discussed as well as a plausible reaction mechanism based on control experiments performed in this work and previous literature reports.
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Lu B. L., Lu J., Shi M. LDA-Mediated Cascade Carbolithiation Reactions of Vinylidenecyclopropanes with Enones and N-Sulfonated Imines as well as Nitroalkene and (Phenylmethylidene)malononitrile // European Journal of Organic Chemistry. 2011. Vol. 2012. No. 3. pp. 587-594.
GOST all authors (up to 50) Copy
Lu B. L., Lu J., Shi M. LDA-Mediated Cascade Carbolithiation Reactions of Vinylidenecyclopropanes with Enones and N-Sulfonated Imines as well as Nitroalkene and (Phenylmethylidene)malononitrile // European Journal of Organic Chemistry. 2011. Vol. 2012. No. 3. pp. 587-594.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1002/ejoc.201101403
UR - https://doi.org/10.1002/ejoc.201101403
TI - LDA-Mediated Cascade Carbolithiation Reactions of Vinylidenecyclopropanes with Enones and N-Sulfonated Imines as well as Nitroalkene and (Phenylmethylidene)malononitrile
T2 - European Journal of Organic Chemistry
AU - Lu, Bei Li
AU - Lu, Jian-Mei
AU - Shi, Min
PY - 2011
DA - 2011/11/28
PB - Wiley
SP - 587-594
IS - 3
VL - 2012
SN - 1434-193X
SN - 1099-0690
ER -
BibTex |
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BibTex (up to 50 authors) Copy
@article{2011_Lu,
author = {Bei Li Lu and Jian-Mei Lu and Min Shi},
title = {LDA-Mediated Cascade Carbolithiation Reactions of Vinylidenecyclopropanes with Enones and N-Sulfonated Imines as well as Nitroalkene and (Phenylmethylidene)malononitrile},
journal = {European Journal of Organic Chemistry},
year = {2011},
volume = {2012},
publisher = {Wiley},
month = {nov},
url = {https://doi.org/10.1002/ejoc.201101403},
number = {3},
pages = {587--594},
doi = {10.1002/ejoc.201101403}
}
MLA
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MLA Copy
Lu, Bei Li, et al. “LDA-Mediated Cascade Carbolithiation Reactions of Vinylidenecyclopropanes with Enones and N-Sulfonated Imines as well as Nitroalkene and (Phenylmethylidene)malononitrile.” European Journal of Organic Chemistry, vol. 2012, no. 3, Nov. 2011, pp. 587-594. https://doi.org/10.1002/ejoc.201101403.