volume 24 issue 10 pages 1945-1955

Modeling Corrosion of Archaeological Silver-Copper Coins Using the Voltammetry of Immobilized Particles

Publication typeJournal Article
Publication date2012-09-05
scimago Q3
wos Q3
SJR0.439
CiteScore6.0
Impact factor2.3
ISSN10400397, 15214109
Analytical Chemistry
Electrochemistry
Abstract
Two complementary models to describe the long-term corrosion of silver-copper coins, based on potential rate laws for smooth corrosion and those combined with diffusive law, for gross corrosion, are proposed. Theoretical kinetics can be tested using signatures of copper and silver corrosion products using the voltammetry of immobilized particles technique. The method is applied to silver coins minted during the 13th–14th centuries from the Libertad street hoard in Valencia (Spain) using non-invasive one-touch graphite pencil sampling. Voltammetric features yield functional dependences in agreement with the proposed model potentially useful for distinguishing between different mints.
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GOST |
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GOST Copy
Doménech A. et al. Modeling Corrosion of Archaeological Silver-Copper Coins Using the Voltammetry of Immobilized Particles // Electroanalysis. 2012. Vol. 24. No. 10. pp. 1945-1955.
GOST all authors (up to 50) Copy
Doménech A., Doménech Carbó M. T., Pasíes T., Del Carmen Bouzas M. Modeling Corrosion of Archaeological Silver-Copper Coins Using the Voltammetry of Immobilized Particles // Electroanalysis. 2012. Vol. 24. No. 10. pp. 1945-1955.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1002/elan.201200252
UR - https://doi.org/10.1002/elan.201200252
TI - Modeling Corrosion of Archaeological Silver-Copper Coins Using the Voltammetry of Immobilized Particles
T2 - Electroanalysis
AU - Doménech, Antonio
AU - Doménech Carbó, María Teresa
AU - Pasíes, Trinidad
AU - Del Carmen Bouzas, María
PY - 2012
DA - 2012/09/05
PB - Wiley
SP - 1945-1955
IS - 10
VL - 24
SN - 1040-0397
SN - 1521-4109
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2012_Doménech,
author = {Antonio Doménech and María Teresa Doménech Carbó and Trinidad Pasíes and María Del Carmen Bouzas},
title = {Modeling Corrosion of Archaeological Silver-Copper Coins Using the Voltammetry of Immobilized Particles},
journal = {Electroanalysis},
year = {2012},
volume = {24},
publisher = {Wiley},
month = {sep},
url = {https://doi.org/10.1002/elan.201200252},
number = {10},
pages = {1945--1955},
doi = {10.1002/elan.201200252}
}
MLA
Cite this
MLA Copy
Doménech, Antonio, et al. “Modeling Corrosion of Archaeological Silver-Copper Coins Using the Voltammetry of Immobilized Particles.” Electroanalysis, vol. 24, no. 10, Sep. 2012, pp. 1945-1955. https://doi.org/10.1002/elan.201200252.