Synthesis of Bridged Bicyclic Molecules using Halocarbenes. Derivatives of bicyclo[4.2.1]nonane
Publication type: Journal Article
Publication date: 1973-04-25
scimago Q2
wos Q3
SJR: 0.491
CiteScore: 3.0
Impact factor: 1.8
ISSN: 0018019X, 15222675
Catalysis
Organic Chemistry
Drug Discovery
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The addition of dichlorocarbene (generated by the interaction of sodium methoxide and ethyl trichloroacetate) to bicyclo[3.2.1]oct-2-ene, its 3-chloro and exo-3,4-dichloro derivatives gives the exo 1 : 1 adducts in yields of 94, 89 and 48%. By suitable chemical reactions of these adducts, convenient syntheses of bicyclo[4.2.1]nona-2,4-diene and bicyclo[4.2.1]non-3-ene, together with their monochloro, dichloro and trichloro derivatives are obtained. Bicyclo[4.2.1]-nonan-3-one is also obtained from bicyclo[4.2.1]non-3-ene in a synthesis starting from the readily available 5-hydroxymethylnorborn-2-ene in an overall yield of 20%.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
2
3
4
|
|
|
Tetrahedron Letters
4 publications, 20%
|
|
|
Chemische Berichte
3 publications, 15%
|
|
|
Tetrahedron
2 publications, 10%
|
|
|
Angewandte Chemie
2 publications, 10%
|
|
|
Helvetica Chimica Acta
2 publications, 10%
|
|
|
Journal of Physical Chemistry A
1 publication, 5%
|
|
|
Organic Letters
1 publication, 5%
|
|
|
Chemischer Informationsdienst
1 publication, 5%
|
|
|
1
2
3
4
|
Publishers
|
1
2
3
4
5
6
7
8
|
|
|
Wiley
8 publications, 40%
|
|
|
Elsevier
6 publications, 30%
|
|
|
American Chemical Society (ACS)
2 publications, 10%
|
|
|
1
2
3
4
5
6
7
8
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
20
Total citations:
20
Citations from 2024:
0
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Jefford C. W., Burger U., Delay F. Synthesis of Bridged Bicyclic Molecules using Halocarbenes. Derivatives of bicyclo[4.2.1]nonane // Helvetica Chimica Acta. 1973. Vol. 56. No. 3. pp. 1083-1096.
GOST all authors (up to 50)
Copy
Jefford C. W., Burger U., Delay F. Synthesis of Bridged Bicyclic Molecules using Halocarbenes. Derivatives of bicyclo[4.2.1]nonane // Helvetica Chimica Acta. 1973. Vol. 56. No. 3. pp. 1083-1096.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/hlca.19730560329
UR - https://doi.org/10.1002/hlca.19730560329
TI - Synthesis of Bridged Bicyclic Molecules using Halocarbenes. Derivatives of bicyclo[4.2.1]nonane
T2 - Helvetica Chimica Acta
AU - Jefford, Charles W.
AU - Burger, Ulrich
AU - Delay, Franois
PY - 1973
DA - 1973/04/25
PB - Wiley
SP - 1083-1096
IS - 3
VL - 56
SN - 0018-019X
SN - 1522-2675
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1973_Jefford,
author = {Charles W. Jefford and Ulrich Burger and Franois Delay},
title = {Synthesis of Bridged Bicyclic Molecules using Halocarbenes. Derivatives of bicyclo[4.2.1]nonane},
journal = {Helvetica Chimica Acta},
year = {1973},
volume = {56},
publisher = {Wiley},
month = {apr},
url = {https://doi.org/10.1002/hlca.19730560329},
number = {3},
pages = {1083--1096},
doi = {10.1002/hlca.19730560329}
}
Cite this
MLA
Copy
Jefford, Charles W., et al. “Synthesis of Bridged Bicyclic Molecules using Halocarbenes. Derivatives of bicyclo[4.2.1]nonane.” Helvetica Chimica Acta, vol. 56, no. 3, Apr. 1973, pp. 1083-1096. https://doi.org/10.1002/hlca.19730560329.