том 79 издание 3 страницы 803-812

Synthesis, and Solution and Solid‐State Structures of (η3‐Allyl){(4S)‐4‐benzyl‐2‐[2′‐(diphenylphosphino)phenyl]‐ 4,5‐dihydrooxazole‐P,N}palladium(II) Hexafluorophosphates. Comparison with Dichloro{(4S)‐2‐[2′‐(diphenylphosphino)phenyl]‐4,5‐dihydro‐4‐phenyloxazole‐P,N}zinc(II)

Тип публикацииJournal Article
Дата публикации1996-05-08
scimago Q2
wos Q3
БС2
SJR0.491
CiteScore3.0
Impact factor1.8
ISSN0018019X, 15222675
Catalysis
Organic Chemistry
Drug Discovery
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
Crystal and solution structures of the [PdII(η3-allyl)] and of the [PdII(η3-1,3-diphenylallyl)] complexes, 4 and 5, respectively, with (4S)-4-benzyl-2-[2′-(diphenylphosphino)phenyl]-4,5-dihydrooxazole (3) were determined by X-ray crystallography and 2D-NMR spectroscopy. Complex 4 proved to be disordered with both diastereoisomeric complexes in the crystal. The results of X-ray and NMR experiments demonstrate a good agreement between solution and solid-state equilibria of the two isomers. A comparison with dichloro{(4S)-2-[2′-(diphenylphosphino)phenyl]-4,5-dihydro-4-phenyloxazole-P,N}zinc(II) (2b) shows a surprising conformational stability of the coordinated phosphinooxazole ligand 3.
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Baltzer N. et al. Synthesis, and Solution and Solid‐State Structures of (η3‐Allyl){(4S)‐4‐benzyl‐2‐[2′‐(diphenylphosphino)phenyl]‐ 4,5‐dihydrooxazole‐P,N}palladium(II) Hexafluorophosphates. Comparison with Dichloro{(4S)‐2‐[2′‐(diphenylphosphino)phenyl]‐4,5‐dihydro‐4‐phenyloxazole‐P,N}zinc(II) // Helvetica Chimica Acta. 1996. Vol. 79. No. 3. pp. 803-812.
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Baltzer N., Macko L., Schaffner S., Zehnder M. Synthesis, and Solution and Solid‐State Structures of (η3‐Allyl){(4S)‐4‐benzyl‐2‐[2′‐(diphenylphosphino)phenyl]‐ 4,5‐dihydrooxazole‐P,N}palladium(II) Hexafluorophosphates. Comparison with Dichloro{(4S)‐2‐[2′‐(diphenylphosphino)phenyl]‐4,5‐dihydro‐4‐phenyloxazole‐P,N}zinc(II) // Helvetica Chimica Acta. 1996. Vol. 79. No. 3. pp. 803-812.
RIS |
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TY - JOUR
DO - 10.1002/hlca.19960790322
UR - https://doi.org/10.1002/hlca.19960790322
TI - Synthesis, and Solution and Solid‐State Structures of (η3‐Allyl){(4S)‐4‐benzyl‐2‐[2′‐(diphenylphosphino)phenyl]‐ 4,5‐dihydrooxazole‐P,N}palladium(II) Hexafluorophosphates. Comparison with Dichloro{(4S)‐2‐[2′‐(diphenylphosphino)phenyl]‐4,5‐dihydro‐4‐phenyloxazole‐P,N}zinc(II)
T2 - Helvetica Chimica Acta
AU - Baltzer, Natalie
AU - Macko, Ludwig
AU - Schaffner, Silvia
AU - Zehnder, Margareta
PY - 1996
DA - 1996/05/08
PB - Wiley
SP - 803-812
IS - 3
VL - 79
SN - 0018-019X
SN - 1522-2675
ER -
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@article{1996_Baltzer,
author = {Natalie Baltzer and Ludwig Macko and Silvia Schaffner and Margareta Zehnder},
title = {Synthesis, and Solution and Solid‐State Structures of (η3‐Allyl){(4S)‐4‐benzyl‐2‐[2′‐(diphenylphosphino)phenyl]‐ 4,5‐dihydrooxazole‐P,N}palladium(II) Hexafluorophosphates. Comparison with Dichloro{(4S)‐2‐[2′‐(diphenylphosphino)phenyl]‐4,5‐dihydro‐4‐phenyloxazole‐P,N}zinc(II)},
journal = {Helvetica Chimica Acta},
year = {1996},
volume = {79},
publisher = {Wiley},
month = {may},
url = {https://doi.org/10.1002/hlca.19960790322},
number = {3},
pages = {803--812},
doi = {10.1002/hlca.19960790322}
}
MLA
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Baltzer, Natalie, et al. “Synthesis, and Solution and Solid‐State Structures of (η3‐Allyl){(4S)‐4‐benzyl‐2‐[2′‐(diphenylphosphino)phenyl]‐ 4,5‐dihydrooxazole‐P,N}palladium(II) Hexafluorophosphates. Comparison with Dichloro{(4S)‐2‐[2′‐(diphenylphosphino)phenyl]‐4,5‐dihydro‐4‐phenyloxazole‐P,N}zinc(II).” Helvetica Chimica Acta, vol. 79, no. 3, May. 1996, pp. 803-812. https://doi.org/10.1002/hlca.19960790322.