volume 1991
,
issue 11
,
pages 1241-1243
Enantioselective synthesis of (S)-(+)-2-tridecanol acetate, an aggregation pheromone component ofDrosophila mulleri
1
Institut für Organische Chemie der Technischen Hochschule Aachen, Professor‐Pirlet‐Straße 1, W‐5100 Aachen
|
Publication type: Journal Article
Publication date: 1991-11-12
—
Organic Chemistry
Physical and Theoretical Chemistry
Abstract
The enantioselective synthesis of (S)-(+)-2-tridecanol acetate [(S)-6] (ee = 93.5%), an aggregation pheromone of Drosophila mulleri, is described. Key steps are the α-alkylation of the propiophenone SAMP-hydrazone (S)-2 (de ≥ 96%) and the Baeyer-Villiger reaction of the ketone (S)-4.
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