volume 56 issue 7 pages 360-363

Automated synthesis and purification of [18F]fluoro-[di-deutero]methyl tosylate

Publication typeJournal Article
Publication date2013-04-17
scimago Q3
wos Q4
SJR0.271
CiteScore2.0
Impact factor0.9
ISSN03624803, 10991344
PubMed ID:  24285440
Organic Chemistry
Drug Discovery
Biochemistry
Spectroscopy
Analytical Chemistry
Radiology, Nuclear Medicine and imaging
Abstract
Automated synthetic procedures of [(18)F]fluoro-[di-deutero]methyl tosylate on a GE TRACERlab FX F-N module and a non-commercial synthesis module have been developed. The syntheses included azeotropic drying of the [(18)F]fluoride, nucleophilic (18)F-fluorination of bis(tosyloxy)-[di-deutero]methane, HPLC purification and subsequent formulation of the synthesized [(18)F]fluoro-[di-deutero]methyl tosylate (d2-[(18)F]FMT) in organic solvents. Automation shortened the total synthesis time to 50 min, resulting in an average radiochemical yield of about 50% and high radiochemical purity (>98%). The possible application of this procedure to commercially available synthesis modules might be of significance for the production of deuterated (18)F-fluoromethylated imaging probes in the future.
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GOST Copy
Beyerlein F. et al. Automated synthesis and purification of [18F]fluoro-[di-deutero]methyl tosylate // Journal of Labelled Compounds and Radiopharmaceuticals. 2013. Vol. 56. No. 7. pp. 360-363.
GOST all authors (up to 50) Copy
Beyerlein F., Piel M., Höhnemann S., Rösch F. Automated synthesis and purification of [18F]fluoro-[di-deutero]methyl tosylate // Journal of Labelled Compounds and Radiopharmaceuticals. 2013. Vol. 56. No. 7. pp. 360-363.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1002/jlcr.3043
UR - https://doi.org/10.1002/jlcr.3043
TI - Automated synthesis and purification of [18F]fluoro-[di-deutero]methyl tosylate
T2 - Journal of Labelled Compounds and Radiopharmaceuticals
AU - Beyerlein, Friederike
AU - Piel, Markus
AU - Höhnemann, Sabine
AU - Rösch, F.
PY - 2013
DA - 2013/04/17
PB - Wiley
SP - 360-363
IS - 7
VL - 56
PMID - 24285440
SN - 0362-4803
SN - 1099-1344
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2013_Beyerlein,
author = {Friederike Beyerlein and Markus Piel and Sabine Höhnemann and F. Rösch},
title = {Automated synthesis and purification of [18F]fluoro-[di-deutero]methyl tosylate},
journal = {Journal of Labelled Compounds and Radiopharmaceuticals},
year = {2013},
volume = {56},
publisher = {Wiley},
month = {apr},
url = {https://doi.org/10.1002/jlcr.3043},
number = {7},
pages = {360--363},
doi = {10.1002/jlcr.3043}
}
MLA
Cite this
MLA Copy
Beyerlein, Friederike, et al. “Automated synthesis and purification of [18F]fluoro-[di-deutero]methyl tosylate.” Journal of Labelled Compounds and Radiopharmaceuticals, vol. 56, no. 7, Apr. 2013, pp. 360-363. https://doi.org/10.1002/jlcr.3043.