Laser and Photonics Reviews, volume 15, issue 10, pages 2100019

Hydrothermal Synthesis of Yb3+: LuLiF4 Microcrystals and Laser Refrigeration of Yb3+: LuLiF4/Silicon‐Nitride Composite Nanostructures

Dobretsova E. 1, 2
Xia Xiaojing 3
Pant Anupum 1
De Siena Michael C 4
Molchanova Anastasia D 5
Novikova Nadezhda N. 6
Klimin Sergei A. 6
Chen Yueyang 7
Majumdar Arka 7, 8
1
 
Department of Materials Science & Engineering University of Washington Seattle WA 98195 USA
3
 
Molecular Engineering and Science Institute University of Washington Seattle WA 98195 USA
4
 
Department of Chemistry University of Washington Seattle WA 98195 USA
7
 
Department of Electrical and Computer Engineering University of Washington Seattle WA 98195 USA
8
 
Department of Physics University of Washington Seattle WA 98195 USA
Publication typeJournal Article
Publication date2021-08-16
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor11
ISSN18638880, 18638899
Electronic, Optical and Magnetic Materials
Atomic and Molecular Physics, and Optics
Condensed Matter Physics
Abstract

The hydrothermal synthesis and characterization of 10%Yb3+:LiLuF4 (LLF) microcrystals are reported. A combination of X‐ray diffraction (XRD) analysis, analytical transmission electron microscopy (TEM), scanning TEM (STEM), energy‐dispersive X‐ray (EDX) spectroscopy), temperature‐dependent Fourier‐transform infrared (FTIR) spectroscopy, and photoluminescence (PL) measurements confirm a scheelite (I41/a) phase and substitutional doping of Yb3+ within the microcrystals. Laser cooling to more than 20 K below room temperature in vacuum (10−3 torr) is demonstrated when irradiating individual microcrystals using a near‐infrared pumping wavelength (λ = 1020nm) at a laser power of 40 mW (irradiance of 0.85 MW cm−2). The use of these microcrystals is further demonstrated for solid‐state laser refrigeration of an electron‐transparent silicon‐nitride (Si3N4) TEM window. A combination of internal luminescence thermometry, heat‐transfer modeling, and control measurements on lithographically patterned Si3N4 optical cavities is used to demonstrate successful bulk laser cooling of Si3N4 TEM windows by ≈15 K below room temperature, opening new opportunities for contactless in situ TEM refrigeration.

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Dobretsova E. et al. Hydrothermal Synthesis of Yb3+: LuLiF4 Microcrystals and Laser Refrigeration of Yb3+: LuLiF4/Silicon‐Nitride Composite Nanostructures // Laser and Photonics Reviews. 2021. Vol. 15. No. 10. p. 2100019.
GOST all authors (up to 50) Copy
Dobretsova E., Xia X., Pant A., Lim M. B., De Siena M. C., Boldyrev K. N., Molchanova A. D., Novikova N. N., Klimin S. A., Попова М. Н., Chen Y., Majumdar A., Gamelin D. R., Pauzauskie P. J. Hydrothermal Synthesis of Yb3+: LuLiF4 Microcrystals and Laser Refrigeration of Yb3+: LuLiF4/Silicon‐Nitride Composite Nanostructures // Laser and Photonics Reviews. 2021. Vol. 15. No. 10. p. 2100019.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1002/lpor.202100019
UR - https://doi.org/10.1002%2Flpor.202100019
TI - Hydrothermal Synthesis of Yb3+: LuLiF4 Microcrystals and Laser Refrigeration of Yb3+: LuLiF4/Silicon‐Nitride Composite Nanostructures
T2 - Laser and Photonics Reviews
AU - Klimin, Sergei A.
AU - Molchanova, Anastasia D
AU - Novikova, Nadezhda N.
AU - Xia, Xiaojing
AU - Pant, Anupum
AU - Gamelin, D. R.
AU - Dobretsova, E.
AU - Lim, Matthew B.
AU - De Siena, Michael C
AU - Boldyrev, Kirill N.
AU - Попова, М. Н.
AU - Chen, Yueyang
AU - Majumdar, Arka
AU - Pauzauskie, Peter J.
PY - 2021
DA - 2021/08/16 00:00:00
PB - Wiley
SP - 2100019
IS - 10
VL - 15
SN - 1863-8880
SN - 1863-8899
ER -
BibTex |
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BibTex Copy
@article{2021_Dobretsova,
author = {Sergei A. Klimin and Anastasia D Molchanova and Nadezhda N. Novikova and Xiaojing Xia and Anupum Pant and D. R. Gamelin and E. Dobretsova and Matthew B. Lim and Michael C De Siena and Kirill N. Boldyrev and М. Н. Попова and Yueyang Chen and Arka Majumdar and Peter J. Pauzauskie},
title = {Hydrothermal Synthesis of Yb3+: LuLiF4 Microcrystals and Laser Refrigeration of Yb3+: LuLiF4/Silicon‐Nitride Composite Nanostructures},
journal = {Laser and Photonics Reviews},
year = {2021},
volume = {15},
publisher = {Wiley},
month = {aug},
url = {https://doi.org/10.1002%2Flpor.202100019},
number = {10},
pages = {2100019},
doi = {10.1002/lpor.202100019}
}
MLA
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MLA Copy
Dobretsova, E., et al. “Hydrothermal Synthesis of Yb3+: LuLiF4 Microcrystals and Laser Refrigeration of Yb3+: LuLiF4/Silicon‐Nitride Composite Nanostructures.” Laser and Photonics Reviews, vol. 15, no. 10, Aug. 2021, p. 2100019. https://doi.org/10.1002%2Flpor.202100019.
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