A Process for Polymerizing Vinyl Phosphonic Acid with C6F13I Perfluoroalkyl Iodide Chain-Transfer Agent
Ghislain David
1
,
Cyrille Boyer
1
,
Russell Tayouo
1
,
Shane Seabrook
1
,
B. Améduri
1
,
Bernard Boutevin
1
,
Gary Woodward
2
,
Mathias Destarac
3
1
Laboratoire d'Ingénierie et Architectures Macromoléculaires (ENSCM)- Institut Charles Gerhardt - UMR(CNRS) 5253, 8 Rue de L'École Normale, 34296 Montpellier Cedex 5, France
|
2
Rhodia Inc, Bristol Research and Technology Center, 350 George Patterson Drive, Bristol PA 19004, USA
|
3
Rhodia Recherches et Technologies, Centre de Recherches et Technologies d'Aubervilliers, 52 rue de la Haie Coq, 93308, Aubervilliers Cedex, France
|
Publication type: Journal Article
Publication date: 2008-01-04
scimago Q2
wos Q3
SJR: 0.569
CiteScore: 4.5
Impact factor: 2.7
ISSN: 10221352, 15213935
Materials Chemistry
Organic Chemistry
Physical and Theoretical Chemistry
Condensed Matter Physics
Polymers and Plastics
Abstract
The synthesis of oligomeric VPA structures via the CTA perfluorohexyl iodide has been investigated. NMR and MALDI-TOF MS analysis showed that the structures were produced exclusively by radical-transfer reactions. The oligomers had a molecular weight above 2 000 g mol -1 and exhibited intra- and intermolecular anhydrous bonding. The investigation showed that the reaction is not a living (controlled) system, but follows conventional radical telomerization. The value for the transfer constant for C 6 F 13 I to VPA was found to be 3.4 at 70°C and 4.3 at 80 °C. This high value may be partially explained by a low k 2 p /k t ratio, which suggests a low k P . The oligomeric structures showed a relatively high resistance to thermal degradation.
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Total citations:
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Citations from 2024:
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(3.33%)
The most citing journal
Citations in journal:
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MLA
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GOST
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David G. et al. A Process for Polymerizing Vinyl Phosphonic Acid with C6F13I Perfluoroalkyl Iodide Chain-Transfer Agent // Macromolecular Chemistry and Physics. 2008. Vol. 209. No. 1. pp. 75-83.
GOST all authors (up to 50)
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David G., Boyer C., Tayouo R., Seabrook S., Améduri B., Boutevin B., Woodward G., Destarac M. A Process for Polymerizing Vinyl Phosphonic Acid with C6F13I Perfluoroalkyl Iodide Chain-Transfer Agent // Macromolecular Chemistry and Physics. 2008. Vol. 209. No. 1. pp. 75-83.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/macp.200700391
UR - https://doi.org/10.1002/macp.200700391
TI - A Process for Polymerizing Vinyl Phosphonic Acid with C6F13I Perfluoroalkyl Iodide Chain-Transfer Agent
T2 - Macromolecular Chemistry and Physics
AU - David, Ghislain
AU - Boyer, Cyrille
AU - Tayouo, Russell
AU - Seabrook, Shane
AU - Améduri, B.
AU - Boutevin, Bernard
AU - Woodward, Gary
AU - Destarac, Mathias
PY - 2008
DA - 2008/01/04
PB - Wiley
SP - 75-83
IS - 1
VL - 209
SN - 1022-1352
SN - 1521-3935
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2008_David,
author = {Ghislain David and Cyrille Boyer and Russell Tayouo and Shane Seabrook and B. Améduri and Bernard Boutevin and Gary Woodward and Mathias Destarac},
title = {A Process for Polymerizing Vinyl Phosphonic Acid with C6F13I Perfluoroalkyl Iodide Chain-Transfer Agent},
journal = {Macromolecular Chemistry and Physics},
year = {2008},
volume = {209},
publisher = {Wiley},
month = {jan},
url = {https://doi.org/10.1002/macp.200700391},
number = {1},
pages = {75--83},
doi = {10.1002/macp.200700391}
}
Cite this
MLA
Copy
David, Ghislain, et al. “A Process for Polymerizing Vinyl Phosphonic Acid with C6F13I Perfluoroalkyl Iodide Chain-Transfer Agent.” Macromolecular Chemistry and Physics, vol. 209, no. 1, Jan. 2008, pp. 75-83. https://doi.org/10.1002/macp.200700391.