Poly(pentafluorobenzyl 2‐ylidene‐acetate): Polymerization and Postpolymerization Modification
Publication type: Journal Article
Publication date: 2022-03-31
scimago Q2
wos Q3
SJR: 0.569
CiteScore: 4.5
Impact factor: 2.7
ISSN: 10221352, 15213935
Materials Chemistry
Organic Chemistry
Physical and Theoretical Chemistry
Condensed Matter Physics
Polymers and Plastics
Abstract
The polymerization of 2,3,4,5,6-pentafluorobenzyl 2-diazoacetate is conducted at ambient temperature and catalyzed by [(l-prolinate)RhI(1,5-dimethyl-1,5-cyclooctadiene)] or [(l-prolinate)RhI(1,5-cyclooctadiene)] yielding C1 polymers with molecular weights of 3000–4000 g mol−1 and dispersity between 1.1 and 1.3. Incorporation of the pentafluorobenzyl group into the C1 polymer results in a different solubility when compare to its C2 analog poly(2,3,4,5,6-pentafluorobenzyl methacrylate). Efficient postmodifications via para-fluoro-thiol reaction with different thiols are conducted with this C1 polymethylene.
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Li Z. et al. Poly(pentafluorobenzyl 2‐ylidene‐acetate): Polymerization and Postpolymerization Modification // Macromolecular Chemistry and Physics. 2022. Vol. 223. No. 9. p. 2100455.
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Li Z., ZHANG H., Théato P., Bräse S. Poly(pentafluorobenzyl 2‐ylidene‐acetate): Polymerization and Postpolymerization Modification // Macromolecular Chemistry and Physics. 2022. Vol. 223. No. 9. p. 2100455.
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TY - JOUR
DO - 10.1002/macp.202100455
UR - https://doi.org/10.1002/macp.202100455
TI - Poly(pentafluorobenzyl 2‐ylidene‐acetate): Polymerization and Postpolymerization Modification
T2 - Macromolecular Chemistry and Physics
AU - Li, Zengwen
AU - ZHANG, Hongxin
AU - Théato, Patrick
AU - Bräse, Stefan
PY - 2022
DA - 2022/03/31
PB - Wiley
SP - 2100455
IS - 9
VL - 223
SN - 1022-1352
SN - 1521-3935
ER -
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BibTex (up to 50 authors)
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@article{2022_Li,
author = {Zengwen Li and Hongxin ZHANG and Patrick Théato and Stefan Bräse},
title = {Poly(pentafluorobenzyl 2‐ylidene‐acetate): Polymerization and Postpolymerization Modification},
journal = {Macromolecular Chemistry and Physics},
year = {2022},
volume = {223},
publisher = {Wiley},
month = {mar},
url = {https://doi.org/10.1002/macp.202100455},
number = {9},
pages = {2100455},
doi = {10.1002/macp.202100455}
}
Cite this
MLA
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Li, Zengwen, et al. “Poly(pentafluorobenzyl 2‐ylidene‐acetate): Polymerization and Postpolymerization Modification.” Macromolecular Chemistry and Physics, vol. 223, no. 9, Mar. 2022, p. 2100455. https://doi.org/10.1002/macp.202100455.