volume 24 issue 15 pages 875-878

Heterogenization of a Modified Grubbs–Hoveyda Catalyst on a ROMP-Derived Monolithic Support

Publication typeJournal Article
Publication date2003-10-22
scimago Q1
wos Q2
SJR1.078
CiteScore8.4
Impact factor4.3
ISSN10221336, 15213927
Materials Chemistry
Organic Chemistry
Polymers and Plastics
Abstract
A ring-opening metathesis polymerization- (ROMP-) based monolith was synthesized using a Grubbs' first generation catalyst. The living termini were used for surface grafting of norborn-5-ene-2-ylmethyl hexafluoroglutarate. The free carboxylic acid groups of the graft polymer were converted into the corresponding silver salt and reacted with the Grubbs-Hoveyda catalyst [RuCl 2 -(=CH-(2-iPrO-)C 6 H 4 )(IMesH 2 )] (IMesH 2 = 1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene) to yield a stable heterogeneous version of this catalyst for use in ring-closing metathesis (RCM) under continuous flow condition. The monolith-supported Grubbs-Hoveyda catalyst.
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GOST |
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GOST Copy
Krause J. O. et al. Heterogenization of a Modified Grubbs–Hoveyda Catalyst on a ROMP-Derived Monolithic Support // Macromolecular Rapid Communications. 2003. Vol. 24. No. 15. pp. 875-878.
GOST all authors (up to 50) Copy
Krause J. O., Lubbad S., Nuyken O., Buchmeiser M. R. Heterogenization of a Modified Grubbs–Hoveyda Catalyst on a ROMP-Derived Monolithic Support // Macromolecular Rapid Communications. 2003. Vol. 24. No. 15. pp. 875-878.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1002/marc.200300024
UR - https://doi.org/10.1002/marc.200300024
TI - Heterogenization of a Modified Grubbs–Hoveyda Catalyst on a ROMP-Derived Monolithic Support
T2 - Macromolecular Rapid Communications
AU - Krause, Jens O
AU - Lubbad, Said
AU - Nuyken, Oskar
AU - Buchmeiser, Michael R.
PY - 2003
DA - 2003/10/22
PB - Wiley
SP - 875-878
IS - 15
VL - 24
SN - 1022-1336
SN - 1521-3927
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2003_Krause,
author = {Jens O Krause and Said Lubbad and Oskar Nuyken and Michael R. Buchmeiser},
title = {Heterogenization of a Modified Grubbs–Hoveyda Catalyst on a ROMP-Derived Monolithic Support},
journal = {Macromolecular Rapid Communications},
year = {2003},
volume = {24},
publisher = {Wiley},
month = {oct},
url = {https://doi.org/10.1002/marc.200300024},
number = {15},
pages = {875--878},
doi = {10.1002/marc.200300024}
}
MLA
Cite this
MLA Copy
Krause, Jens O., et al. “Heterogenization of a Modified Grubbs–Hoveyda Catalyst on a ROMP-Derived Monolithic Support.” Macromolecular Rapid Communications, vol. 24, no. 15, Oct. 2003, pp. 875-878. https://doi.org/10.1002/marc.200300024.