Enhanced mechanical and tribological properties of 3D printed short carbon fiber reinforced polyether ether ketone composites

Material extrusion additive manufacturing provides an effective solution for fabrication of highly customized polyether ether ketone (PEEK) composite parts with any complex shape. Nevertheless, compared with conventional methods, the mechanical strength of 3D printed carbon fiber reinforced PEEK (CF/PEEK) composites is unsatisfactory due to the weak interface bonding strength and high voids content induced by the temperature difference. To overcome this challenge, a temperature‐control 3D printer was used to investigate the effects of ambient temperature and annealing temperature on the microstructure, crystallization behavior and mechanical properties of 3D printed parts. Moreover, the tribological properties of parts printed at different ambient temperature were also studied under various contact pressure. Experimental results showed that the ambient temperature and annealing treatment directly affected the interfacial bonding (fiber/matrix, filament/filament, layer/layer), crystallinity of printed samples, thus affecting their mechanical and tribological properties. The CF/PEEK parts printed at high ambient temperature of 200°C exhibited outstanding mechanical and tribological properties. This study has positive significance for promoting the application of 3D printed PEEK composites in the field of structural load‐bearing and friction materials.