Thermal Study on Picryl Azide (2-azido-1,3,5-trinitrobenzene) decomposition using simultaneous thermogravimetry and differential scanning calorimetry
1
Research and Development Division, IDL Chemicals Limited, Hyderabad 500 018 A.P. (India)
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Publication type: Journal Article
Publication date: 1983-02-01
scimago Q2
wos Q3
SJR: 0.461
CiteScore: 3.9
Impact factor: 2.0
ISSN: 07213115, 15214087
General Chemistry
General Chemical Engineering
Abstract
Thermal decomposition of picryl azide has been studied under non-isothermal and isothermal conditions using a simultaneous TG-DSC technique. Picryl azide melts and then decomposes to give 4,6-dinitrobenzofurazan oxide which melts again and decomposes to gaseous products. Enthalpies (ΔH) of fusion and decomposition have been calculated. The order of reaction (n) is calculated and found to be one. Arrhenius parameters like specific rate constant (k), activation energy (Eact) and frequency factor (Z) have been calculated under both conditions using different methods. The values calculated from non-isothermal and isothermal techniques agree fairly well with each other. The observed lower activation energy when compared with phenylazide and 2-nitrophenyl azide is probably due to an enhanced ortho effect.
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Total citations:
8
Citations from 2024:
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(12.5%)
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Reddy G., Murali B. K. M., Chatterjee A. Thermal Study on Picryl Azide (2-azido-1,3,5-trinitrobenzene) decomposition using simultaneous thermogravimetry and differential scanning calorimetry // Propellants, Explosives, Pyrotechnics. 1983. Vol. 8. No. 1. pp. 29-33.
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Reddy G., Murali B. K. M., Chatterjee A. Thermal Study on Picryl Azide (2-azido-1,3,5-trinitrobenzene) decomposition using simultaneous thermogravimetry and differential scanning calorimetry // Propellants, Explosives, Pyrotechnics. 1983. Vol. 8. No. 1. pp. 29-33.
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TY - JOUR
DO - 10.1002/prep.19830080107
UR - https://doi.org/10.1002/prep.19830080107
TI - Thermal Study on Picryl Azide (2-azido-1,3,5-trinitrobenzene) decomposition using simultaneous thermogravimetry and differential scanning calorimetry
T2 - Propellants, Explosives, Pyrotechnics
AU - Reddy, G.Om
AU - Murali, B K Mohan
AU - Chatterjee, A.
PY - 1983
DA - 1983/02/01
PB - Wiley
SP - 29-33
IS - 1
VL - 8
SN - 0721-3115
SN - 1521-4087
ER -
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BibTex (up to 50 authors)
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@article{1983_Reddy,
author = {G.Om Reddy and B K Mohan Murali and A. Chatterjee},
title = {Thermal Study on Picryl Azide (2-azido-1,3,5-trinitrobenzene) decomposition using simultaneous thermogravimetry and differential scanning calorimetry},
journal = {Propellants, Explosives, Pyrotechnics},
year = {1983},
volume = {8},
publisher = {Wiley},
month = {feb},
url = {https://doi.org/10.1002/prep.19830080107},
number = {1},
pages = {29--33},
doi = {10.1002/prep.19830080107}
}
Cite this
MLA
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Reddy, G.Om, et al. “Thermal Study on Picryl Azide (2-azido-1,3,5-trinitrobenzene) decomposition using simultaneous thermogravimetry and differential scanning calorimetry.” Propellants, Explosives, Pyrotechnics, vol. 8, no. 1, Feb. 1983, pp. 29-33. https://doi.org/10.1002/prep.19830080107.