Binding of azole fungicides related to diclobutrazol to cytochrome P-450
1
ICIp.I.c., Plant Protection Division, Jealott's Hill Research Station, Bracknell, Berkshire RG12 6EY
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Тип публикации: Journal Article
Дата публикации: 1984-04-01
Applied Microbiology and Biotechnology
Краткое описание
Fungicides containing the imidazole and triazole groups are known to block the 14α-demethylation reaction in ergosterol biosynthesis, which is a cytochrome P-450 enzyme system. Fungicides related to diclobutrazol [(2RS, 3RS)-1-(2,4-dichlorophenyl)-4,4-dimethyl-2-(1,2,4-triazol-1-yl)pentan-3-ol] bind to cytochrome P-450 in rat liver microsomes, whole yeast cells, yeast microsomes and to a partially purified cytochrome P-450 from yeast, with Type II spectral changes. The most fungicidally active isomer (2R, 3R) shows greater binding than the less active (2S, 3S)-enantiomer to yeast microsomes; when the cytochrome P-450 was purified, a preparation was obtained to which binding more closely matched the fungicidal activity. Binding to rat liver microsomes does not reflect the fungicidal activity of the compounds.
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WIGGINS T. E., Baldwin B. C. Binding of azole fungicides related to diclobutrazol to cytochrome P-450 // Pesticide Science. 1984. Vol. 15. No. 2. pp. 206-209.
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WIGGINS T. E., Baldwin B. C. Binding of azole fungicides related to diclobutrazol to cytochrome P-450 // Pesticide Science. 1984. Vol. 15. No. 2. pp. 206-209.
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TY - JOUR
DO - 10.1002/ps.2780150212
UR - https://doi.org/10.1002/ps.2780150212
TI - Binding of azole fungicides related to diclobutrazol to cytochrome P-450
T2 - Pesticide Science
AU - WIGGINS, THOMAS E.
AU - Baldwin, Brian C
PY - 1984
DA - 1984/04/01
PB - Wiley
SP - 206-209
IS - 2
VL - 15
SN - 0031-613X
SN - 1096-9063
ER -
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@article{1984_WIGGINS,
author = {THOMAS E. WIGGINS and Brian C Baldwin},
title = {Binding of azole fungicides related to diclobutrazol to cytochrome P-450},
journal = {Pesticide Science},
year = {1984},
volume = {15},
publisher = {Wiley},
month = {apr},
url = {https://doi.org/10.1002/ps.2780150212},
number = {2},
pages = {206--209},
doi = {10.1002/ps.2780150212}
}
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MLA
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WIGGINS, THOMAS E., and Brian C Baldwin. “Binding of azole fungicides related to diclobutrazol to cytochrome P-450.” Pesticide Science, vol. 15, no. 2, Apr. 1984, pp. 206-209. https://doi.org/10.1002/ps.2780150212.