Synthesis of New Energetic Materials Based on Furazan Rings and Nitro‐ NNO ‐azoxy Groups
Nikita E Leonov
1
,
Michael S Klenov
1
,
Oleg V Anikin
1
,
Yurii A. Strelenko
1
,
Alexey A Voronin
1
,
David Lempert
2
,
Nikita Muravyev
3
,
Ivan V. Fedyanin
4, 5
,
Sergei E Semenov
1, 6
,
Vladimir A Tartakovsky
1
6
Moscow Chemical Lyceum 4 Tamozhenniy proezd 111033 Moscow, Russian Federation
|
Publication type: Journal Article
Publication date: 2020-10-16
General Chemistry
Abstract
Energetic compounds 1–6, consisting of one or two furazan rings linked by azo or azoxy bridges and one or two nitro‐NNO‐azoxy substituents, were synthesized by nitration of the corresponding tert‐butyl‐NNO‐azoxy precursors with NO2BF4. Novel methods for the synthesis of 3,4‐bis(tert‐butyl‐NNO‐azoxy)furazan (7) and bis‐4,4′‐(tert‐butyl‐NNO‐azoxy)‐3,3′‐azoxyfurazan (21) were elaborated. The nitro‐NNO‐azoxy compounds obtained display high calculated detonation performance (vD=8.07–9.40 km s−1 and PC‐J=27.4–43.4 GPa) that is superior to the corresponding nitrofurazans (DNF, DNAzF, DNAF). The replacement of nitrofurazans with the corresponding (nitro‐NNO‐azoxy)furazans increases the specific impulse of the model solid composite propellant formulations by 2–10 s, which is due to high calculated heats of formation (600–892 kcal kg−1) and positive oxygen balance (0–20 %) of the latter compounds.
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33
Total citations:
33
Citations from 2025:
11
(33.33%)
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GOST
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Leonov N. E. et al. Synthesis of New Energetic Materials Based on Furazan Rings and Nitro‐ NNO ‐azoxy Groups // ChemistrySelect. 2020. Vol. 5. No. 39. pp. 12243-12249.
GOST all authors (up to 50)
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Leonov N. E., Klenov M. S., Anikin O. V., Churakov A. M., Strelenko Y. A., Voronin A. A., Lempert D., Muravyev N., Fedyanin I. V., Semenov S. E., Tartakovsky V. A. Synthesis of New Energetic Materials Based on Furazan Rings and Nitro‐ NNO ‐azoxy Groups // ChemistrySelect. 2020. Vol. 5. No. 39. pp. 12243-12249.
Cite this
RIS
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TY - JOUR
DO - 10.1002/slct.202003182
UR - https://doi.org/10.1002/slct.202003182
TI - Synthesis of New Energetic Materials Based on Furazan Rings and Nitro‐ NNO ‐azoxy Groups
T2 - ChemistrySelect
AU - Leonov, Nikita E
AU - Klenov, Michael S
AU - Anikin, Oleg V
AU - Churakov, Aleksandr M
AU - Strelenko, Yurii A.
AU - Voronin, Alexey A
AU - Lempert, David
AU - Muravyev, Nikita
AU - Fedyanin, Ivan V.
AU - Semenov, Sergei E
AU - Tartakovsky, Vladimir A
PY - 2020
DA - 2020/10/16
PB - Wiley
SP - 12243-12249
IS - 39
VL - 5
SN - 2365-6549
ER -
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BibTex (up to 50 authors)
Copy
@article{2020_Leonov,
author = {Nikita E Leonov and Michael S Klenov and Oleg V Anikin and Aleksandr M Churakov and Yurii A. Strelenko and Alexey A Voronin and David Lempert and Nikita Muravyev and Ivan V. Fedyanin and Sergei E Semenov and Vladimir A Tartakovsky},
title = {Synthesis of New Energetic Materials Based on Furazan Rings and Nitro‐ NNO ‐azoxy Groups},
journal = {ChemistrySelect},
year = {2020},
volume = {5},
publisher = {Wiley},
month = {oct},
url = {https://doi.org/10.1002/slct.202003182},
number = {39},
pages = {12243--12249},
doi = {10.1002/slct.202003182}
}
Cite this
MLA
Copy
Leonov, Nikita E., et al. “Synthesis of New Energetic Materials Based on Furazan Rings and Nitro‐ NNO ‐azoxy Groups.” ChemistrySelect, vol. 5, no. 39, Oct. 2020, pp. 12243-12249. https://doi.org/10.1002/slct.202003182.