Hydrogen Bond‐Assisted Macrocyclic Synthesis: An Extended Application For 4‐Hydroxybenzylamine Derivatives
Publication type: Journal Article
Publication date: 2024-09-09
Abstract
This work involved synthesizing three N ‐benzyl‐4‐hydroxybenzylamines using indirect reductive amination of aromatic aldehydes and 4‐hydroxybenzylamine. Such benzylamines’ reaction with formaldehyde produced tricyclic azacyclophanes formed by two benzylamine units joined by methylene bridges. Computational calculations established that macrocyclization was promoted by template formation stabilized by hydrogen bonds and π‐stacking.
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Gonzalez-Oñate A., Flores Gaspar A., Quevedo R. Hydrogen Bond‐Assisted Macrocyclic Synthesis: An Extended Application For 4‐Hydroxybenzylamine Derivatives // ChemistrySelect. 2024. Vol. 9. No. 34. e202402715
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Gonzalez-Oñate A., Flores Gaspar A., Quevedo R. Hydrogen Bond‐Assisted Macrocyclic Synthesis: An Extended Application For 4‐Hydroxybenzylamine Derivatives // ChemistrySelect. 2024. Vol. 9. No. 34. e202402715
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TY - JOUR
DO - 10.1002/slct.202402715
UR - https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/slct.202402715
TI - Hydrogen Bond‐Assisted Macrocyclic Synthesis: An Extended Application For 4‐Hydroxybenzylamine Derivatives
T2 - ChemistrySelect
AU - Gonzalez-Oñate, Andrés
AU - Flores Gaspar, Areli
AU - Quevedo, Rodolfo
PY - 2024
DA - 2024/09/09
PB - Wiley
IS - 34
VL - 9
SN - 2365-6549
ER -
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@article{2024_Gonzalez-Oñate,
author = {Andrés Gonzalez-Oñate and Areli Flores Gaspar and Rodolfo Quevedo},
title = {Hydrogen Bond‐Assisted Macrocyclic Synthesis: An Extended Application For 4‐Hydroxybenzylamine Derivatives},
journal = {ChemistrySelect},
year = {2024},
volume = {9},
publisher = {Wiley},
month = {sep},
url = {https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/slct.202402715},
number = {34},
pages = {e202402715},
doi = {10.1002/slct.202402715}
}