, pages 331-376

Exciplex: Its Nature and Application to OLEDs

Hwang-Beom Kim ¹

Hyun Min Kim ²

Dongwook Kim ³

Dong Wook Kim ⁴

Jang-Joo Kim ⁵

Hide authors affiliations Show authors affiliations: 5 affiliations

Seoul National University; Department of Materials Science and Engineering; 1 Gwanak-ro, Gwanak-gu Seoul 151-744 South Korea |

Seoul National University, Department of Materials Science and Engineering, 1 Gwanak-ro, Gwanak-gu, Seoul, 151-744 South Korea |

Kyonggi University; Department of Chemistry; 154-42 Gwanggyosan-Ro, Yeongtong-Gu Suwon 16227 South Korea |

⁴

Kyonggi University, Department of Chemistry, 154-42 Gwanggyosan-Ro, Yeongtong-Gu, Suwon, 16227 South Korea |

⁵

Seoul National University, Department of Materials Science and Engineering and Research Institute of Advanced Materials (RIAM), 1 Gwanak-ro, Gwanak-gu, Seoul, 151-744 South Korea |

Publication type: Book Chapter

Publication date: 2018-10-05

Wiley

DOI: 10.1002/9783527691722.ch10

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Abstract

Exciplexes have been widely employed in organic light-emitting diodes (OLEDs) by virtue of the thermally activated delayed fluorescence (TADF) characteristics and the convenience of exploiting exciplexes to OLEDs. Exciplexes are readily formed when the blend films of donor molecules and acceptor molecules are excited. We treat the fundamentals of exciplexes and their application to OLEDs in this chapter. First, the electronic structures and properties of exciplexes and various transition processes associated with exciplex systems are covered. Later, OLEDs employing exciplexes as emitters as well as sensitizers are reviewe.

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