Open Access
A Novel Metastable Pentavalent Plutonium Solid Phase on the Pathway from Aqueous Plutonium(VI) to PuO2 Nanoparticles
Kristina Kvashnina
1, 2, 3, 4
,
Anna Romanchuk
5, 6
,
Ivan Pidchenko
1, 2, 3, 4
,
Lucia Amidani
1, 2, 3, 4
,
Evgeny Gerber
1, 2, 3, 4, 5, 6
,
Andre Rossberg
1, 2, 3, 4
,
Stephan Weiss
2, 4
,
Karin Popa
8, 9
,
Olaf Walter
8, 9
,
R. Caciuffo
8, 9
,
Andreas C. Scheinost
1, 2, 3, 4
,
Sergei M. Butorin
10, 11
,
Stepan N. Kalmykov
5, 6, 7
8
Directorate for Nuclear Safety and SecurityEuropean Commission, Joint Research Centre Postfach 2340 76215 Karlsruhe Germany
|
9
Directorate for Nuclear Safety and Security European Commission, Joint Research Centre Postfach 2340 76215 Karlsruhe Germany
|
Publication type: Journal Article
Publication date: 2019-11-06
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
31621992
General Chemistry
Catalysis
Abstract
Here we provide evidence that the formation of PuO2 nanoparticles from oxidized PuVI under alkaline conditions proceeds through the formation of an intermediate PuV solid phase, similar to NH4PuO2CO3, which is stable over a period of several months. For the first time, state‐of‐the‐art experiments at Pu M4 and at L3 absorption edges combined with theoretical calculations unambiguously allow to determine the oxidation state and the local structure of this intermediate phase.
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Metrics
47
Total citations:
47
Citations from 2025:
9
(19.57%)
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MLA
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GOST
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Kvashnina K. et al. A Novel Metastable Pentavalent Plutonium Solid Phase on the Pathway from Aqueous Plutonium(VI) to PuO2 Nanoparticles // Angewandte Chemie - International Edition. 2019. Vol. 58. No. 49. pp. 17558-17562.
GOST all authors (up to 50)
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Kvashnina K., Romanchuk A., Pidchenko I., Amidani L., Gerber E., Trigub A. L., Rossberg A., Weiss S., Popa K., Walter O., Caciuffo R., Scheinost A. C., Butorin S. M., Kalmykov S. N. A Novel Metastable Pentavalent Plutonium Solid Phase on the Pathway from Aqueous Plutonium(VI) to PuO2 Nanoparticles // Angewandte Chemie - International Edition. 2019. Vol. 58. No. 49. pp. 17558-17562.
Cite this
RIS
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TY - JOUR
DO - 10.1002/ANIE.201911637
UR - https://onlinelibrary.wiley.com/doi/10.1002/anie.201911637
TI - A Novel Metastable Pentavalent Plutonium Solid Phase on the Pathway from Aqueous Plutonium(VI) to PuO2 Nanoparticles
T2 - Angewandte Chemie - International Edition
AU - Kvashnina, Kristina
AU - Romanchuk, Anna
AU - Pidchenko, Ivan
AU - Amidani, Lucia
AU - Gerber, Evgeny
AU - Trigub, Alexander L.
AU - Rossberg, Andre
AU - Weiss, Stephan
AU - Popa, Karin
AU - Walter, Olaf
AU - Caciuffo, R.
AU - Scheinost, Andreas C.
AU - Butorin, Sergei M.
AU - Kalmykov, Stepan N.
PY - 2019
DA - 2019/11/06
PB - Wiley
SP - 17558-17562
IS - 49
VL - 58
PMID - 31621992
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2019_Kvashnina,
author = {Kristina Kvashnina and Anna Romanchuk and Ivan Pidchenko and Lucia Amidani and Evgeny Gerber and Alexander L. Trigub and Andre Rossberg and Stephan Weiss and Karin Popa and Olaf Walter and R. Caciuffo and Andreas C. Scheinost and Sergei M. Butorin and Stepan N. Kalmykov},
title = {A Novel Metastable Pentavalent Plutonium Solid Phase on the Pathway from Aqueous Plutonium(VI) to PuO2 Nanoparticles},
journal = {Angewandte Chemie - International Edition},
year = {2019},
volume = {58},
publisher = {Wiley},
month = {nov},
url = {https://onlinelibrary.wiley.com/doi/10.1002/anie.201911637},
number = {49},
pages = {17558--17562},
doi = {10.1002/ANIE.201911637}
}
Cite this
MLA
Copy
Kvashnina, Kristina, et al. “A Novel Metastable Pentavalent Plutonium Solid Phase on the Pathway from Aqueous Plutonium(VI) to PuO2 Nanoparticles.” Angewandte Chemie - International Edition, vol. 58, no. 49, Nov. 2019, pp. 17558-17562. https://onlinelibrary.wiley.com/doi/10.1002/anie.201911637.