Wiley
Chemistry - A European Journal
,  том 25 ,  издание 72 ,  страницы 16550-16554

Mild, Selective Ru‐Catalyzed Deuteration Using D 2 O as a Deuterium Source

Тип публикации: Journal Article
Дата публикации: 2019-11-28
Wiley
scimago Q1
wos Q2
БС1
SJR: 0.981
CiteScore: 6.7
Impact factor: 3.7
ISSN: 09476539, 15213765
General Chemistry
Catalysis
Organic Chemistry
Краткое описание
A method for the selective deuteration of polyfunctional organic molecules using catalytic amounts of [RuCl2 (PPh3 )3 ] and D2 O as a deuterium source is presented. Through variation of additives like CuI, KOH, and various amounts of zinc powder, orthogonal chemoselectivities in the deuteration process are observed. Mechanistic investigation indicates the presence of different, defined Ru-complexes under the given specific conditions.
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Eisele P. et al. Mild, Selective Ru‐Catalyzed Deuteration Using D 2 O as a Deuterium Source // Chemistry - A European Journal. 2019. Vol. 25. No. 72. pp. 16550-16554.
ГОСТ со всеми авторами (до 50) Скопировать
Eisele P., Ullwer F., Scholz S., Plietker B. Mild, Selective Ru‐Catalyzed Deuteration Using D 2 O as a Deuterium Source // Chemistry - A European Journal. 2019. Vol. 25. No. 72. pp. 16550-16554.
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TY - JOUR
DO - 10.1002/chem.201904927
UR - https://doi.org/10.1002/chem.201904927
TI - Mild, Selective Ru‐Catalyzed Deuteration Using D 2 O as a Deuterium Source
T2 - Chemistry - A European Journal
AU - Eisele, Pascal
AU - Ullwer, Franziska
AU - Scholz, Sven
AU - Plietker, Bernd
PY - 2019
DA - 2019/11/28
PB - Wiley
SP - 16550-16554
IS - 72
VL - 25
PMID - 31680359
SN - 0947-6539
SN - 1521-3765
ER -
BibTex |
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@article{2019_Eisele,
author = {Pascal Eisele and Franziska Ullwer and Sven Scholz and Bernd Plietker},
title = {Mild, Selective Ru‐Catalyzed Deuteration Using D 2 O as a Deuterium Source},
journal = {Chemistry - A European Journal},
year = {2019},
volume = {25},
publisher = {Wiley},
month = {nov},
url = {https://doi.org/10.1002/chem.201904927},
number = {72},
pages = {16550--16554},
doi = {10.1002/chem.201904927}
}
MLA
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Eisele, Pascal, et al. “Mild, Selective Ru‐Catalyzed Deuteration Using D 2 O as a Deuterium Source.” Chemistry - A European Journal, vol. 25, no. 72, Nov. 2019, pp. 16550-16554. https://doi.org/10.1002/chem.201904927.