Ruthenium-Catalyzed Methylation of Amines with Paraformaldehyde in Water under Mild Conditions
Publication type: Journal Article
Publication date: 2016-08-05
scimago Q1
wos Q1
SJR: 1.845
CiteScore: 13.1
Impact factor: 6.6
ISSN: 18645631, 1864564X
PubMed ID:
27491504
General Chemical Engineering
General Materials Science
General Energy
Environmental Chemistry
Abstract
Methylated amines are highly important for a variety of pharmaceutical and agrochemical applications. Existing routes for their formation result in the production of large amounts of waste or require high reaction temperatures, both of which impact the ecological and economical footprint of the methodologies. Herein, we report the ruthenium-catalyzed reductive methylation of a range of aliphatic amines, using paraformaldehyde as both substrate and hydrogen source, in combination with water. This reaction proceeds under mild aqueous reaction conditions. Additionally the use of a secondary phase for catalyst retention and recycling has been investigated with promising results.
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Total citations:
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Citations from 2024:
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(26.92%)
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GOST
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Van Der Waals D. et al. Ruthenium-Catalyzed Methylation of Amines with Paraformaldehyde in Water under Mild Conditions // ChemSusChem. 2016. Vol. 9. No. 17. pp. 2343-2347.
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Van Der Waals D., Heim L. E., Gedig C., Herbrik F., Vallazza S., Prechtl M. Ruthenium-Catalyzed Methylation of Amines with Paraformaldehyde in Water under Mild Conditions // ChemSusChem. 2016. Vol. 9. No. 17. pp. 2343-2347.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/cssc.201600824
UR - https://doi.org/10.1002/cssc.201600824
TI - Ruthenium-Catalyzed Methylation of Amines with Paraformaldehyde in Water under Mild Conditions
T2 - ChemSusChem
AU - Van Der Waals, Dominic
AU - Heim, Leo E
AU - Gedig, Christian
AU - Herbrik, Fabian
AU - Vallazza, Simona
AU - Prechtl, Martin
PY - 2016
DA - 2016/08/05
PB - Wiley
SP - 2343-2347
IS - 17
VL - 9
PMID - 27491504
SN - 1864-5631
SN - 1864-564X
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2016_Van Der Waals,
author = {Dominic Van Der Waals and Leo E Heim and Christian Gedig and Fabian Herbrik and Simona Vallazza and Martin Prechtl},
title = {Ruthenium-Catalyzed Methylation of Amines with Paraformaldehyde in Water under Mild Conditions},
journal = {ChemSusChem},
year = {2016},
volume = {9},
publisher = {Wiley},
month = {aug},
url = {https://doi.org/10.1002/cssc.201600824},
number = {17},
pages = {2343--2347},
doi = {10.1002/cssc.201600824}
}
Cite this
MLA
Copy
Van Der Waals, Dominic, et al. “Ruthenium-Catalyzed Methylation of Amines with Paraformaldehyde in Water under Mild Conditions.” ChemSusChem, vol. 9, no. 17, Aug. 2016, pp. 2343-2347. https://doi.org/10.1002/cssc.201600824.