Preparation ofC2-Symmetric Bis[2-(diphenylphosphino)ferrocen-1-yl]- methane and Its Use in Rhodium- and Ruthenium-Catalyzed Hydrogenation
2
Institute of Chemical Technologies and Analytics, Vienna University of Technology, Getreidemarkt 9, A-1060 Vienna
|
3
Solvias AG, WKL 127, P. O. Box, CH‐4002 Basel
|
Publication type: Journal Article
Publication date: 2006-08-30
scimago Q2
wos Q3
SJR: 0.491
CiteScore: 3.0
Impact factor: 1.8
ISSN: 0018019X, 15222675
Catalysis
Organic Chemistry
Drug Discovery
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The two diphosphine ligands (Rp,Rp)- and (Sp,Sp)-bis[2-(diphenylphospino)ferrocenyl]methane, (Rp,Rp)- and (Sp,Sp)-1, resp., were prepared in six steps from (S)- and (R)-ferrocenyl tolyl sulfoxide, respectively (Scheme). In the solid state, both the diborane complex (Rp,Rp)-1 ⋅ (BH3)2 and the palladium dichloride complex [PdCl2((Rp,Rp)-1)] were found to adopt C2-pseudosymmetric structures according to X-ray analyses (Figs. 2 and 3). In the Rh- and Ru-catalyzed hydrogenation of selected alkenes and ketones in the presence of the new ligands, enantioselectivities of up to 55% ee were obtained.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
2
3
|
|
|
Organometallics
3 publications, 23.08%
|
|
|
MolBank
2 publications, 15.38%
|
|
|
Acta crystallographica. Section C, Structural chemistry
1 publication, 7.69%
|
|
|
Coordination Chemistry Reviews
1 publication, 7.69%
|
|
|
European Journal of Organic Chemistry
1 publication, 7.69%
|
|
|
Dalton Transactions
1 publication, 7.69%
|
|
|
Chemical Reviews
1 publication, 7.69%
|
|
|
Russian Chemical Reviews
1 publication, 7.69%
|
|
|
1
2
3
|
Publishers
|
1
2
3
4
|
|
|
American Chemical Society (ACS)
4 publications, 30.77%
|
|
|
MDPI
2 publications, 15.38%
|
|
|
Wiley
2 publications, 15.38%
|
|
|
International Union of Crystallography (IUCr)
1 publication, 7.69%
|
|
|
Elsevier
1 publication, 7.69%
|
|
|
Royal Society of Chemistry (RSC)
1 publication, 7.69%
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 7.69%
|
|
|
1
2
3
4
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
13
Total citations:
13
Citations from 2024:
2
(15.38%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Wang Y. et al. Preparation ofC2-Symmetric Bis[2-(diphenylphosphino)ferrocen-1-yl]- methane and Its Use in Rhodium- and Ruthenium-Catalyzed Hydrogenation // Helvetica Chimica Acta. 2006. Vol. 89. No. 8. pp. 1772-1782.
GOST all authors (up to 50)
Copy
Wang Y., Weissensteiner W., Mereiter K., Spindler F. Preparation ofC2-Symmetric Bis[2-(diphenylphosphino)ferrocen-1-yl]- methane and Its Use in Rhodium- and Ruthenium-Catalyzed Hydrogenation // Helvetica Chimica Acta. 2006. Vol. 89. No. 8. pp. 1772-1782.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/hlca.200690173
UR - https://doi.org/10.1002/hlca.200690173
TI - Preparation ofC2-Symmetric Bis[2-(diphenylphosphino)ferrocen-1-yl]- methane and Its Use in Rhodium- and Ruthenium-Catalyzed Hydrogenation
T2 - Helvetica Chimica Acta
AU - Wang, Yaping
AU - Weissensteiner, Walter
AU - Mereiter, K.
AU - Spindler, Felix
PY - 2006
DA - 2006/08/30
PB - Wiley
SP - 1772-1782
IS - 8
VL - 89
SN - 0018-019X
SN - 1522-2675
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2006_Wang,
author = {Yaping Wang and Walter Weissensteiner and K. Mereiter and Felix Spindler},
title = {Preparation ofC2-Symmetric Bis[2-(diphenylphosphino)ferrocen-1-yl]- methane and Its Use in Rhodium- and Ruthenium-Catalyzed Hydrogenation},
journal = {Helvetica Chimica Acta},
year = {2006},
volume = {89},
publisher = {Wiley},
month = {aug},
url = {https://doi.org/10.1002/hlca.200690173},
number = {8},
pages = {1772--1782},
doi = {10.1002/hlca.200690173}
}
Cite this
MLA
Copy
Wang, Yaping, et al. “Preparation ofC2-Symmetric Bis[2-(diphenylphosphino)ferrocen-1-yl]- methane and Its Use in Rhodium- and Ruthenium-Catalyzed Hydrogenation.” Helvetica Chimica Acta, vol. 89, no. 8, Aug. 2006, pp. 1772-1782. https://doi.org/10.1002/hlca.200690173.