Benzotriazinyl-mediated controlled radical polymerization of styrene
Publication type: Journal Article
Publication date: 2013-07-08
scimago Q2
wos Q2
SJR: 0.636
CiteScore: 7.3
Impact factor: 3.6
ISSN: 09598103, 10970126
DOI:
10.1002/pi.4566
Materials Chemistry
Organic Chemistry
Polymers and Plastics
Abstract
The stable free radical polymerization (SFRP) process based on (1,3-diphenyl-1,4-dihydro-1,2,4-benzotriazin-4-yl), the so-called ‘Blatter radical’, and several C-7 substituted derivatives is introduced for the first time for the polymerization of styrene. Polystyrenes characterized by polydispersity indices in the 1.05 − 1.27 range were obtained in the presence of the Blatter radical and its derivatives containing CF3, Ph, Fur-2-yl and 4-PhC6H4 substituents, while polymerization proceeded either in a non-controlled manner or in very low polymerization yields in the presence of derivatives containing halogen (Cl, Br, I) substituents. This preliminary investigation, demonstrating the potential use of the Blatter radical and its derivatives in mediated SFRP, creates new opportunities to design and develop radicals to optimize performance in such polymerization processes. © 2013 Society of Chemical Industry
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58
Total citations:
58
Citations from 2024:
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(6.89%)
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MLA
Cite this
GOST
Copy
Demetriou M. et al. Benzotriazinyl-mediated controlled radical polymerization of styrene // Polymer International. 2013. Vol. 63. No. 4. pp. 674-679.
GOST all authors (up to 50)
Copy
Demetriou M., Berezin A. A., Koutentis P. A., Krasia Christoforou T. Benzotriazinyl-mediated controlled radical polymerization of styrene // Polymer International. 2013. Vol. 63. No. 4. pp. 674-679.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/pi.4566
UR - https://doi.org/10.1002/pi.4566
TI - Benzotriazinyl-mediated controlled radical polymerization of styrene
T2 - Polymer International
AU - Demetriou, Maria
AU - Berezin, Andrey A
AU - Koutentis, Panayiotis A.
AU - Krasia Christoforou, Theodora
PY - 2013
DA - 2013/07/08
PB - Wiley
SP - 674-679
IS - 4
VL - 63
SN - 0959-8103
SN - 1097-0126
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2013_Demetriou,
author = {Maria Demetriou and Andrey A Berezin and Panayiotis A. Koutentis and Theodora Krasia Christoforou},
title = {Benzotriazinyl-mediated controlled radical polymerization of styrene},
journal = {Polymer International},
year = {2013},
volume = {63},
publisher = {Wiley},
month = {jul},
url = {https://doi.org/10.1002/pi.4566},
number = {4},
pages = {674--679},
doi = {10.1002/pi.4566}
}
Cite this
MLA
Copy
Demetriou, Maria, et al. “Benzotriazinyl-mediated controlled radical polymerization of styrene.” Polymer International, vol. 63, no. 4, Jul. 2013, pp. 674-679. https://doi.org/10.1002/pi.4566.