Sulfenylation of Indoles Mediated by Iodine and Its Compounds
Indole represents one of the most common and important heterocyclic scaffolds omnipresent in a plenty of natural products and medicinal agents. Development of the synthetic routes to 3‐substituted indoles attracts a considerable attention due to a huge amount of biologically relevant molecules containing 3‐substituted indole moiety. Reactions of indoles halogenation, nitration, acylation, and alkylation at the 3d position have been known for several decades and continue developing now. Processes of indoles sulfenylation are much less studied. However, 3‐sulfenylated derivatives possess promising biological properties. This review summarizes nearly 100 references from the middle of the 20th century to 2021, concerning reactions of indoles sulfenylation mediated by iodine and its compounds. The manuscript is divided into the sections according to the classes of compounds used as sulfenylating agents.
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American Chemical Society (ACS)
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Royal Society of Chemistry (RSC)
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