Advanced Functional Materials, volume 21, issue 20, pages 3859-3867

Electrochemical Na Insertion and Solid Electrolyte Interphase for Hard-Carbon Electrodes and Application to Na-Ion Batteries

Publication typeJournal Article
Publication date2011-08-11
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor19
ISSN1616301X, 16163028
Electronic, Optical and Magnetic Materials
Electrochemistry
Condensed Matter Physics
Biomaterials
Abstract
Recently, lithium-ion batteries have been attracting more interest for use in automotive applications. Lithium resources are confirmed to be unevenly distributed in South America, and the cost of the lithium raw materials has roughly doubled from the first practical application in 1991 to the present and is increasing due to global demand for lithium-ion accumulators. Since the electrochemical equivalent and standard potential of sodium are the most advantageous after lithium, sodium based energy storage is of great interest to realize lithium-free high energy and high voltage batteries. However, to the best of our knowledge, there have been no successful reports on electrochemical sodium insertion materials for battery applications; the major challenge is the negative electrode and its passivation. In this study, we achieve high capacity and excellent reversibility sodium-insertion performance of hard-carbon and layered NaNi0.5Mn0.5O2 electrodes in propylene carbonate electrolyte solutions. The structural change and passivation for hard-carbon are investigated to study the reversible sodium insertion. The 3-volt secondary Na-ion battery possessing environmental and cost friendliness, Na+-shuttlecock hard-carbon/NaNi0.5Mn0.5O2 cell, demonstrates steady cycling performance as next generation secondary batteries and an alternative to Li-ion batteries.

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GOST |
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GOST Copy
Komaba S. et al. Electrochemical Na Insertion and Solid Electrolyte Interphase for Hard-Carbon Electrodes and Application to Na-Ion Batteries // Advanced Functional Materials. 2011. Vol. 21. No. 20. pp. 3859-3867.
GOST all authors (up to 50) Copy
Komaba S., Murata W., Ishikawa T., Yabuuchi N., Ozeki T., Nakayama T., Ogata A., Gotoh K., Fujiwara K. Electrochemical Na Insertion and Solid Electrolyte Interphase for Hard-Carbon Electrodes and Application to Na-Ion Batteries // Advanced Functional Materials. 2011. Vol. 21. No. 20. pp. 3859-3867.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1002/adfm.201100854
UR - https://doi.org/10.1002/adfm.201100854
TI - Electrochemical Na Insertion and Solid Electrolyte Interphase for Hard-Carbon Electrodes and Application to Na-Ion Batteries
T2 - Advanced Functional Materials
AU - Komaba, Shin-ichi
AU - Murata, Wataru
AU - Ishikawa, Toru
AU - Yabuuchi, Naoaki
AU - Ozeki, Tomoaki
AU - Nakayama, Tetsuri
AU - Ogata, Atsushi
AU - Gotoh, Kazuma
AU - Fujiwara, Kazuya
PY - 2011
DA - 2011/08/11 00:00:00
PB - Wiley
SP - 3859-3867
IS - 20
VL - 21
SN - 1616-301X
SN - 1616-3028
ER -
BibTex |
Cite this
BibTex Copy
@article{2011_Komaba,
author = {Shin-ichi Komaba and Wataru Murata and Toru Ishikawa and Naoaki Yabuuchi and Tomoaki Ozeki and Tetsuri Nakayama and Atsushi Ogata and Kazuma Gotoh and Kazuya Fujiwara},
title = {Electrochemical Na Insertion and Solid Electrolyte Interphase for Hard-Carbon Electrodes and Application to Na-Ion Batteries},
journal = {Advanced Functional Materials},
year = {2011},
volume = {21},
publisher = {Wiley},
month = {aug},
url = {https://doi.org/10.1002/adfm.201100854},
number = {20},
pages = {3859--3867},
doi = {10.1002/adfm.201100854}
}
MLA
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MLA Copy
Komaba, Shin-ichi, et al. “Electrochemical Na Insertion and Solid Electrolyte Interphase for Hard-Carbon Electrodes and Application to Na-Ion Batteries.” Advanced Functional Materials, vol. 21, no. 20, Aug. 2011, pp. 3859-3867. https://doi.org/10.1002/adfm.201100854.
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