Advanced Functional Materials, volume 28, issue 1, pages 1703952
Photoswitchable Nanomaterials Based on Hierarchically Organized Siloxane Oligomers
Zha R Helen
1
,
Vantomme Ghislaine
1
,
Berrocal José Augusto
1
,
Gosens Ronald
1
,
de Waal Bas
1
,
Meskers S.C.J.
1
,
Meijer E. W.
1
Publication type: Journal Article
Publication date: 2017-11-07
Journal:
Advanced Functional Materials
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 19
ISSN: 1616301X
Electronic, Optical and Magnetic Materials
Electrochemistry
Condensed Matter Physics
Biomaterials
Abstract
Materials with highly ordered molecular arrangements have the capacity to display unique properties derived from their nanoscale structure. Here, the synthesis and characterization of azobenzene (AZO)-functionalized siloxane oligomers of discrete length that form photoswitchable supramolecular materials are described. Specifically, synergy between phase segregation and azobenzene crystallization leads to the self-assembly of an exfoliated 2D crystal that becomes isotropic upon photoisomerization with UV light. Consequently, the material undergoes a rapid athermal solid-to-liquid transition which can be reversed using blue light due to the unexpectedly fast 2D crystallization that is facilitated by phase segregation. In contrast, enabling telechelic supramolecular polymerization through hydrogen bonding inhibits azobenzene crystallization, and nanostructured pastes with well-ordered morphologies are obtained based on phase segregation alone, thus demonstrating block copolymer-like behavior. Therefore, by tailoring the balance of self-assembly forces in the azobenzene-functionalized siloxane oligomers, fast and reversible phase-changing materials can be engineered with various mechanical properties for applications in photolithography or switchable adhesion to lubricant properties.
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1
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Citations by publishers
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5
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15
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25
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23 publications, 27.06%
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Elsevier
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The Chemical Society of Japan
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1 publication, 1.18%
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1 publication, 1.18%
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Taylor & Francis
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1 publication, 1.18%
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1 publication, 1.18%
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Trans Tech Publications
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Trans Tech Publications
1 publication, 1.18%
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5
10
15
20
25
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Zha R. H. et al. Photoswitchable Nanomaterials Based on Hierarchically Organized Siloxane Oligomers // Advanced Functional Materials. 2017. Vol. 28. No. 1. p. 1703952.
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Zha R. H., Vantomme G., Berrocal J. A., Gosens R., de Waal B., Meskers S., Meijer E. W. Photoswitchable Nanomaterials Based on Hierarchically Organized Siloxane Oligomers // Advanced Functional Materials. 2017. Vol. 28. No. 1. p. 1703952.
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TY - JOUR
DO - 10.1002/adfm.201703952
UR - https://doi.org/10.1002%2Fadfm.201703952
TI - Photoswitchable Nanomaterials Based on Hierarchically Organized Siloxane Oligomers
T2 - Advanced Functional Materials
AU - Gosens, Ronald
AU - de Waal, Bas
AU - Meijer, E. W.
AU - Zha, R Helen
AU - Vantomme, Ghislaine
AU - Berrocal, José Augusto
AU - Meskers, S.C.J.
PY - 2017
DA - 2017/11/07 00:00:00
PB - Wiley
SP - 1703952
IS - 1
VL - 28
SN - 1616-301X
ER -
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@article{2017_Zha,
author = {Ronald Gosens and Bas de Waal and E. W. Meijer and R Helen Zha and Ghislaine Vantomme and José Augusto Berrocal and S.C.J. Meskers},
title = {Photoswitchable Nanomaterials Based on Hierarchically Organized Siloxane Oligomers},
journal = {Advanced Functional Materials},
year = {2017},
volume = {28},
publisher = {Wiley},
month = {nov},
url = {https://doi.org/10.1002%2Fadfm.201703952},
number = {1},
pages = {1703952},
doi = {10.1002/adfm.201703952}
}
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MLA
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Zha, R. Helen, et al. “Photoswitchable Nanomaterials Based on Hierarchically Organized Siloxane Oligomers.” Advanced Functional Materials, vol. 28, no. 1, Nov. 2017, p. 1703952. https://doi.org/10.1002%2Fadfm.201703952.