Advanced Functional Materials, volume 30, issue 46, pages 2006289
Effective Optimization of High Voltage Solid‐State Lithium Batteries by Using Poly(ethylene oxide)‐Based Polymer Electrolyte with Semi‐Interpenetrating Network
1
Publication type: Journal Article
Publication date: 2020-08-23
Journal:
Advanced Functional Materials
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 19
ISSN: 1616301X, 16163028
Electronic, Optical and Magnetic Materials
Electrochemistry
Condensed Matter Physics
Biomaterials
Abstract
Solid polymer electrolytes (SPEs) are promising candidates for the realization of lithium metal batteries. However, the popular SPE based on poly(ethylene oxide) (PEO) reveals a “voltage noise”-failure during charge, for example, with high energy/high voltage electrodes like LiNi0.6Mn0.2Co0.2O2 (NMC622), which can be attributed to short-circuits via penetrating Li dendrites. This failure disappears when integrating PEO-based SPE in a semi interpenetrating network, which mainly consists of PEO units, as well. In this work, it is shown that this SPE allows performance improvement via elimination of the crystalline domains without significant sacrifice of mechanical integrity. Hence, a highly amorphous SPE can be obtained by a simple increase of plasticizing Li salts, which overall is beneficial, not only for the ionic conductivity, but also the homogeneity, while remaining mechanically stable and solid in its original shape even after storage at 60 °C for 7 days. These aspects are crucial for the performance of the modified SPE as they can suppress the failure-causing Li dendrite penetration while the electrochemical aspects, that is, anodic stability, are rather unaffected by the modification and remain stable (4.6 V vs Li│Li+). Overall, this optimized SPE enables stable cycling performance in NMC622│SPE│Li cells, even at 40 °C operation temperature.
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Citations by publishers
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1 publication, 1%
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5
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Homann G. et al. Effective Optimization of High Voltage Solid‐State Lithium Batteries by Using Poly(ethylene oxide)‐Based Polymer Electrolyte with Semi‐Interpenetrating Network // Advanced Functional Materials. 2020. Vol. 30. No. 46. p. 2006289.
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Homann G., Stolz L., Neuhaus K., Winter M., Kasnatscheew J. Effective Optimization of High Voltage Solid‐State Lithium Batteries by Using Poly(ethylene oxide)‐Based Polymer Electrolyte with Semi‐Interpenetrating Network // Advanced Functional Materials. 2020. Vol. 30. No. 46. p. 2006289.
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TY - JOUR
DO - 10.1002/adfm.202006289
UR - https://doi.org/10.1002/adfm.202006289
TI - Effective Optimization of High Voltage Solid‐State Lithium Batteries by Using Poly(ethylene oxide)‐Based Polymer Electrolyte with Semi‐Interpenetrating Network
T2 - Advanced Functional Materials
AU - Stolz, Lukas
AU - Kasnatscheew, Johannes
AU - Homann, Gerrit
AU - Neuhaus, K.
AU - Winter, Martin
PY - 2020
DA - 2020/08/23 00:00:00
PB - Wiley
SP - 2006289
IS - 46
VL - 30
SN - 1616-301X
SN - 1616-3028
ER -
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@article{2020_Homann,
author = {Lukas Stolz and Johannes Kasnatscheew and Gerrit Homann and K. Neuhaus and Martin Winter},
title = {Effective Optimization of High Voltage Solid‐State Lithium Batteries by Using Poly(ethylene oxide)‐Based Polymer Electrolyte with Semi‐Interpenetrating Network},
journal = {Advanced Functional Materials},
year = {2020},
volume = {30},
publisher = {Wiley},
month = {aug},
url = {https://doi.org/10.1002/adfm.202006289},
number = {46},
pages = {2006289},
doi = {10.1002/adfm.202006289}
}
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MLA
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Homann, Gerrit, et al. “Effective Optimization of High Voltage Solid‐State Lithium Batteries by Using Poly(ethylene oxide)‐Based Polymer Electrolyte with Semi‐Interpenetrating Network.” Advanced Functional Materials, vol. 30, no. 46, Aug. 2020, p. 2006289. https://doi.org/10.1002/adfm.202006289.