Advanced Functional Materials, volume 32, issue 29, pages 2201136

Boron Nitride‐Based Release Agent Coating Stabilizes Li _1.3 Al _0.3 Ti _1.7 (PO ₄ ) ₃ /Li Interface with Superior Lean‐Lithium Electrochemical Performance and Thermal Stability

Lei Zhu ^{1, 2}

Youwei Wang ³

Yongmin Wu ²

Wuliang Feng ¹

Zhaolin Liu ⁴

Weiping Tang ²

Xiaowei Wang ⁴

Yong-Yao Xia ¹

Hide authors affiliations Show authors affiliations: 4 affiliations

Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials Institute of New Energy iChEM (Collaborative Innovation Center of Chemistry for Energy Materials) Fudan University Shanghai 200433 P. R. China |

State Key Laboratory of Space Power‐Sources Technology Shanghai Institute of Space Power‐Sources Shanghai 200245 P. R. China |

State Key Laboratory of High Performance Ceramics and Superfine Microstructure Shanghai Institute of Ceramics Chinese Academy of Sciences Shanghai 200050 P. R. China |

⁴

Institute of Materials Research and Engineering (IMRE) A*STAR 2 Fusionopolis Way Innovis 138634 Singapore |

Publication type: Journal Article

Publication date: 2022-04-20

Wiley

Journal: Advanced Functional Materials

Quartile SCImago

Quartile WOS

Impact factor: 19

ISSN: 1616301X, 16163028

DOI: 10.1002/adfm.202201136

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Electronic, Optical and Magnetic Materials

Electrochemistry

Condensed Matter Physics

Biomaterials

Abstract

Sodium super ionic conductor (NASICON)-type Li1.3Al0.3Ti1.7(PO4)3 (LATP) is one of the most promising solid-state electrolytes (SSEs) owing to its high Li-ion conductivity, high stability with air, and low cost. However, LATP is less widely deployed due to its high incompatibility with lithium metal. Herein, a facile and inexpensive spray-coating approach is proposed to construct a thin 3D organic/inorganic composite layer of a commercial boron nitride-based release agent (BNRA) onto LATP. Apart from protecting LATP, this interfacial BNRA layer enables Li-ion migration through BN defects and affords low resistance at BNRA/Li interface due to in situ formation of Li–N. Compared to bare LATP, which fails to support Li stripping–plating process in a lean-lithium Li/Li symmetric cell (2 µm), BNRA-LATP runs for ≈1800 h. The assembled lean-lithium LiFePO4 (LFP)/BNRA-LATP/Li solid state batteries (SSBs) deliver a specific capacity of 150.9 mA h g–1 at 0.5 C with minor capacity decay after 500 cycles. Besides, the BNRA layer eliminates thermal runaway risks of LATP-based SSBs by fast in-plane thermal dispersion. This work demonstrates a facile LATP-protection strategy regarding Li incompatibility and thermal runway issues, and pinpoints the interfacial formation mechanism, fulfilling the pursuit of high-performance low-cost SSEs.

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Advanced Energy Materials	Advanced Energy Materials, 5, 13.16% Advanced Energy Materials 5 publications, 13.16%
InfoMat	InfoMat, 2, 5.26% InfoMat 2 publications, 5.26%
Chemical Engineering Journal	Chemical Engineering Journal, 2, 5.26% Chemical Engineering Journal 2 publications, 5.26%
Frontiers in Chemistry	Frontiers in Chemistry, 1, 2.63% Frontiers in Chemistry 1 publication, 2.63%
Electrochimica Acta	Electrochimica Acta, 1, 2.63% Electrochimica Acta 1 publication, 2.63%
ChemSusChem	ChemSusChem, 1, 2.63% ChemSusChem 1 publication, 2.63%
ACS Energy Letters	ACS Energy Letters, 1, 2.63% ACS Energy Letters 1 publication, 2.63%
New Journal of Chemistry	New Journal of Chemistry, 1, 2.63% New Journal of Chemistry 1 publication, 2.63%
Journal of Materials Chemistry A	Journal of Materials Chemistry A, 1, 2.63% Journal of Materials Chemistry A 1 publication, 2.63%
APL Materials	APL Materials, 1, 2.63% APL Materials 1 publication, 2.63%
Nano Research	Nano Research, 1, 2.63% Nano Research 1 publication, 2.63%
Progress in Materials Science	Progress in Materials Science, 1, 2.63% Progress in Materials Science 1 publication, 2.63%
ACS applied materials & interfaces	ACS applied materials & interfaces, 1, 2.63% ACS applied materials & interfaces 1 publication, 2.63%
Journal of Colloid and Interface Science	Journal of Colloid and Interface Science, 1, 2.63% Journal of Colloid and Interface Science 1 publication, 2.63%
Energy Storage Materials	Energy Storage Materials, 1, 2.63% Energy Storage Materials 1 publication, 2.63%
Ceramics International	Ceramics International, 1, 2.63% Ceramics International 1 publication, 2.63%
ACS Nano	ACS Nano, 1, 2.63% ACS Nano 1 publication, 2.63%
Green Chemistry	Green Chemistry, 1, 2.63% Green Chemistry 1 publication, 2.63%
Chemical Science	Chemical Science, 1, 2.63% Chemical Science 1 publication, 2.63%
Journal of Power Sources	Journal of Power Sources, 1, 2.63% Journal of Power Sources 1 publication, 2.63%
Surface and Coatings Technology	Surface and Coatings Technology, 1, 2.63% Surface and Coatings Technology 1 publication, 2.63%
Carbon Energy	Carbon Energy, 1, 2.63% Carbon Energy 1 publication, 2.63%
Advanced Functional Materials	Advanced Functional Materials, 1, 2.63% Advanced Functional Materials 1 publication, 2.63%
Advanced Materials	Advanced Materials, 1, 2.63% Advanced Materials 1 publication, 2.63%
ACS Applied Energy Materials	ACS Applied Energy Materials, 1, 2.63% ACS Applied Energy Materials 1 publication, 2.63%
Advanced Science	Advanced Science, 1, 2.63% Advanced Science 1 publication, 2.63%
eScience	eScience, 1, 2.63% eScience 1 publication, 2.63%
Small	Small, 1, 2.63% Small 1 publication, 2.63%
Energy & Environmental Materials	Energy & Environmental Materials, 1, 2.63% Energy & Environmental Materials 1 publication, 2.63%
Interdisciplinary Materials	Interdisciplinary Materials, 1, 2.63% Interdisciplinary Materials 1 publication, 2.63%
	1 2 3 4 5

Citations by publishers

	2 4 6 8 10 12 14 16
Wiley	Wiley, 15, 39.47% Wiley 15 publications, 39.47%
Elsevier	Elsevier, 11, 28.95% Elsevier 11 publications, 28.95%
American Chemical Society (ACS)	American Chemical Society (ACS), 4, 10.53% American Chemical Society (ACS) 4 publications, 10.53%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 4, 10.53% Royal Society of Chemistry (RSC) 4 publications, 10.53%
Frontiers Media S.A.	Frontiers Media S.A., 1, 2.63% Frontiers Media S.A. 1 publication, 2.63%
American Institute of Physics (AIP)	American Institute of Physics (AIP), 1, 2.63% American Institute of Physics (AIP) 1 publication, 2.63%
Springer Nature	Springer Nature, 1, 2.63% Springer Nature 1 publication, 2.63%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 2.63% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 2.63%
	2 4 6 8 10 12 14 16

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Zhu L. et al. Boron Nitride‐Based Release Agent Coating Stabilizes Li 1.3 Al 0.3 Ti 1.7 (PO 4 ) 3 /Li Interface with Superior Lean‐Lithium Electrochemical Performance and Thermal Stability // Advanced Functional Materials. 2022. Vol. 32. No. 29. p. 2201136.

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Zhu L., Wang Y., Wu Y., Feng W., Liu Z., Tang W., Wang X., Xia Y. Boron Nitride‐Based Release Agent Coating Stabilizes Li 1.3 Al 0.3 Ti 1.7 (PO 4 ) 3 /Li Interface with Superior Lean‐Lithium Electrochemical Performance and Thermal Stability // Advanced Functional Materials. 2022. Vol. 32. No. 29. p. 2201136.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1002/adfm.202201136

UR - https://doi.org/10.1002/adfm.202201136

TI - Boron Nitride‐Based Release Agent Coating Stabilizes Li 1.3 Al 0.3 Ti 1.7 (PO 4 ) 3 /Li Interface with Superior Lean‐Lithium Electrochemical Performance and Thermal Stability

T2 - Advanced Functional Materials

AU - Wang, Youwei

AU - Wu, Yongmin

AU - Liu, Zhaolin

AU - Tang, Weiping

AU - Wang, Xiaowei

AU - Xia, Yong-Yao

AU - Zhu, Lei

AU - Feng, Wuliang

PY - 2022

DA - 2022/04/20 00:00:00

PB - Wiley

SP - 2201136

IS - 29

VL - 32

SN - 1616-301X

SN - 1616-3028

ER -

BibTex |

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BibTex Copy

@article{2022_Zhu,

author = {Youwei Wang and Yongmin Wu and Zhaolin Liu and Weiping Tang and Xiaowei Wang and Yong-Yao Xia and Lei Zhu and Wuliang Feng},

title = {Boron Nitride‐Based Release Agent Coating Stabilizes Li 1.3 Al 0.3 Ti 1.7 (PO 4 ) 3 /Li Interface with Superior Lean‐Lithium Electrochemical Performance and Thermal Stability},

journal = {Advanced Functional Materials},

year = {2022},

volume = {32},

publisher = {Wiley},

month = {apr},

url = {https://doi.org/10.1002/adfm.202201136},

number = {29},

pages = {2201136},

doi = {10.1002/adfm.202201136}

}

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MLA Copy

Zhu, Lei, et al. “Boron Nitride‐Based Release Agent Coating Stabilizes Li 1.3 Al 0.3 Ti 1.7 (PO 4 ) 3 /Li Interface with Superior Lean‐Lithium Electrochemical Performance and Thermal Stability.” Advanced Functional Materials, vol. 32, no. 29, Apr. 2022, p. 2201136. https://doi.org/10.1002/adfm.202201136.

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Publisher

Wiley

Journal

Advanced Functional Materials

Quartile SCImago

Quartile WOS

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ISSN

1616301X (Print)
16163028 (Electronic)