Advanced Functional Materials, volume 32, issue 25, pages 2201465

Vertically Heterostructured Solid Electrolytes for Lithium Metal Batteries

Fei He ¹

Zhenglin Hu ¹

Wenjing Tang ¹

Aoxuan Wang ¹

Bohua Wen ²

Lan Zhang ³

Jinrong Luo ^{1, 4}

Hide authors affiliations Show authors affiliations: 4 affiliations

Key Laboratory for Green Chemical Technology of Ministry of Education School of Chemical Engineering and Technology Tianjin University Tianjin 300072 China |

Shenzhen International Graduate School Tsinghua University Shenzhen 518055 China |

CAS Key Laboratory of Green Process and Engineering Beijing Key Laboratory of Ionic Liquids Clean Process State Key Laboratory of Multiphase Complex Systems Institute of Process Engineering Chinese Academy of Sciences Beijing 100190 China |

⁴

Shanghai Key Lab of Advanced High‐Temperature Materials and Precision Forming School of Materials Science and Engineering Shanghai Jiao Tong University Shanghai 200240 China |

Publication type: Journal Article

Publication date: 2022-04-12

Wiley

Journal: Advanced Functional Materials

Quartile SCImago

Quartile WOS

Impact factor: 19

ISSN: 1616301X, 16163028

DOI: 10.1002/adfm.202201465

Copy DOI

Electronic, Optical and Magnetic Materials

Electrochemistry

Condensed Matter Physics

Biomaterials

Abstract

Solid-state electrolytes (SSEs) have been regarded as the most attractive candidate for safe and high-energy lithium (Li) batteries of the next generation. However, the inability of current SSEs to keep up with the performance requirements of batteries is significantly affected by complex factors, especially ionic conductivity, mechanochemical properties, and coupled ion/electron reaction at the electrified interfaces. Strategies in solid electrolyte chemistries and technologies are put forward to overcome these challenges while widening the breadth of possible applications. Among them, vertically heterostructured solid-state electrolytes (HSE) are constructed as a most promising strategy, which can take advantage of individual SSE layers together and rationalize the stability and compatibility of electrodes. This review comprehensively summarizes the specific features of the HSE based on the current knowledge of SSE failure modes. Additionally, a detailed review of the recent progress on the HSE design in terms of organic polymer electrolytes and inorganic electrolytes is generated. Finally, the advantages and drawbacks of the design strategies are discussed. New perspectives about HSE are proposed as well.

By date By citations

Top-30

Citations by journals

	1 2
Materials Today Energy	Materials Today Energy, 2, 6.25% Materials Today Energy 2 publications, 6.25%
Chemical Engineering Journal	Chemical Engineering Journal, 2, 6.25% Chemical Engineering Journal 2 publications, 6.25%
ACS applied materials & interfaces	ACS applied materials & interfaces, 2, 6.25% ACS applied materials & interfaces 2 publications, 6.25%
Angewandte Chemie - International Edition	Angewandte Chemie - International Edition, 2, 6.25% Angewandte Chemie - International Edition 2 publications, 6.25%
Angewandte Chemie	Angewandte Chemie, 2, 6.25% Angewandte Chemie 2 publications, 6.25%
Nano-Micro Letters	Nano-Micro Letters, 1, 3.13% Nano-Micro Letters 1 publication, 3.13%
Advanced Energy Materials	Advanced Energy Materials, 1, 3.13% Advanced Energy Materials 1 publication, 3.13%
Small	Small, 1, 3.13% Small 1 publication, 3.13%
Journal of Colloid and Interface Science	Journal of Colloid and Interface Science, 1, 3.13% Journal of Colloid and Interface Science 1 publication, 3.13%
Batteries & Supercaps	Batteries & Supercaps, 1, 3.13% Batteries & Supercaps 1 publication, 3.13%
Small Methods	Small Methods, 1, 3.13% Small Methods 1 publication, 3.13%
Energy & Environmental Materials	Energy & Environmental Materials, 1, 3.13% Energy & Environmental Materials 1 publication, 3.13%
Advanced Materials	Advanced Materials, 1, 3.13% Advanced Materials 1 publication, 3.13%
Advanced Functional Materials	Advanced Functional Materials, 1, 3.13% Advanced Functional Materials 1 publication, 3.13%
Chemical Science	Chemical Science, 1, 3.13% Chemical Science 1 publication, 3.13%
Journal of Physical Chemistry C	Journal of Physical Chemistry C, 1, 3.13% Journal of Physical Chemistry C 1 publication, 3.13%
Energy Storage Materials	Energy Storage Materials, 1, 3.13% Energy Storage Materials 1 publication, 3.13%
Chemical Communications	Chemical Communications, 1, 3.13% Chemical Communications 1 publication, 3.13%
Electrochemical Energy Reviews	Electrochemical Energy Reviews, 1, 3.13% Electrochemical Energy Reviews 1 publication, 3.13%
Advanced Nanocomposites	Advanced Nanocomposites, 1, 3.13% Advanced Nanocomposites 1 publication, 3.13%
ACS Applied Energy Materials	ACS Applied Energy Materials, 1, 3.13% ACS Applied Energy Materials 1 publication, 3.13%
ACS Materials Letters	ACS Materials Letters, 1, 3.13% ACS Materials Letters 1 publication, 3.13%
ACS Nano	ACS Nano, 1, 3.13% ACS Nano 1 publication, 3.13%
Advanced Science	Advanced Science, 1, 3.13% Advanced Science 1 publication, 3.13%
Nano Energy	Nano Energy, 1, 3.13% Nano Energy 1 publication, 3.13%
Energies	Energies, 1, 3.13% Energies 1 publication, 3.13%
Russian Chemical Reviews	Russian Chemical Reviews, 1, 3.13% Russian Chemical Reviews 1 publication, 3.13%
	1 2

Citations by publishers

	2 4 6 8 10 12
Wiley	Wiley, 12, 37.5% Wiley 12 publications, 37.5%
Elsevier	Elsevier, 8, 25% Elsevier 8 publications, 25%
American Chemical Society (ACS)	American Chemical Society (ACS), 6, 18.75% American Chemical Society (ACS) 6 publications, 18.75%
Springer Nature	Springer Nature, 2, 6.25% Springer Nature 2 publications, 6.25%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 2, 6.25% Royal Society of Chemistry (RSC) 2 publications, 6.25%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 1, 3.13% Multidisciplinary Digital Publishing Institute (MDPI) 1 publication, 3.13%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 3.13% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 3.13%
	2 4 6 8 10 12

We do not take into account publications without a DOI.
Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
Statistics recalculated weekly.

{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2022,2023,2024],"ids":[0,0,0],"codes":[0,0,0],"imageUrls":["","",""],"datasets":[{"label":"Citations number","data":[4,13,15],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6"],"percentage":["12.5","40.63","46.88"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Materials Today Energy","Chemical Engineering Journal","ACS applied materials & interfaces","Angewandte Chemie - International Edition","Angewandte Chemie","Nano-Micro Letters","Advanced Energy Materials","Small","Journal of Colloid and Interface Science","Batteries & Supercaps","Small Methods","Energy & Environmental Materials","Advanced Materials","Advanced Functional Materials","Chemical Science","Journal of Physical Chemistry C","Energy Storage Materials","Chemical Communications","Electrochemical Energy Reviews","Advanced Nanocomposites","ACS Applied Energy Materials","ACS Materials Letters","ACS Nano","Advanced Science","Nano Energy","Energies","Russian Chemical Reviews"],"ids":[15323,16275,1458,19215,25450,7765,22475,9872,24202,26456,4145,26479,25159,7715,9646,8859,3858,9073,25884,54775,6419,13131,8724,4130,23236,23828,23802],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp"],"datasets":[{"label":"","data":[2,2,2,2,2,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[6.25,6.25,6.25,6.25,6.25,3.13,3.13,3.13,3.13,3.13,3.13,3.13,3.13,3.13,3.13,3.13,3.13,3.13,3.13,3.13,3.13,3.13,3.13,3.13,3.13,3.13,3.13],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Wiley","Elsevier","American Chemical Society (ACS)","Springer Nature","Royal Society of Chemistry (RSC)","Multidisciplinary Digital Publishing Institute (MDPI)","Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii"],"ids":[11,17,40,8,123,202,9422],"codes":[0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp"],"datasets":[{"label":"","data":[12,8,6,2,2,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[37.5,25,18.75,6.25,6.25,3.13,3.13],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartiles":{"type":"bar","data":{"show":true,"labels":[2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,0],"percentage":["0","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,0,0],"percentage":["0","0","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[0,0,0],"percentage":["0","0","0"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[4,13,14],"percentage":["12.5","40.63","43.75"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,0,1],"percentage":["0","0","3.13"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by SCImago per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartilesWs":{"type":"bar","data":{"show":true,"labels":[2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,0],"percentage":["0","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,0,1],"percentage":["0","0","3.13"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[1,1,1],"percentage":["3.13","3.13","3.13"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[2,12,11],"percentage":["6.25","37.5","34.38"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[1,0,2],"percentage":["3.13","0","6.25"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by WoS per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}

Are you a researcher?

Create a profile to get free access to personal recommendations for colleagues and new articles.

Metrics

Cite this

GOST |

Cite this

GOST Copy

He F. et al. Vertically Heterostructured Solid Electrolytes for Lithium Metal Batteries // Advanced Functional Materials. 2022. Vol. 32. No. 25. p. 2201465.

GOST all authors (up to 50) Copy

He F., Hu Z., Tang W., Wang A., Wen B., Zhang L., Luo J. Vertically Heterostructured Solid Electrolytes for Lithium Metal Batteries // Advanced Functional Materials. 2022. Vol. 32. No. 25. p. 2201465.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1002/adfm.202201465

UR - https://doi.org/10.1002/adfm.202201465

TI - Vertically Heterostructured Solid Electrolytes for Lithium Metal Batteries

T2 - Advanced Functional Materials

AU - Hu, Zhenglin

AU - Wang, Aoxuan

AU - Wen, Bohua

AU - Luo, Jinrong

AU - He, Fei

AU - Tang, Wenjing

AU - Zhang, Lan

PY - 2022

DA - 2022/04/12 00:00:00

PB - Wiley

SP - 2201465

IS - 25

VL - 32

SN - 1616-301X

SN - 1616-3028

ER -

BibTex |

Cite this

BibTex Copy

@article{2022_He,

author = {Zhenglin Hu and Aoxuan Wang and Bohua Wen and Jinrong Luo and Fei He and Wenjing Tang and Lan Zhang},

title = {Vertically Heterostructured Solid Electrolytes for Lithium Metal Batteries},

journal = {Advanced Functional Materials},

year = {2022},

volume = {32},

publisher = {Wiley},

month = {apr},

url = {https://doi.org/10.1002/adfm.202201465},

number = {25},

pages = {2201465},

doi = {10.1002/adfm.202201465}

}

MLA

Cite this

MLA Copy

He, Fei, et al. “Vertically Heterostructured Solid Electrolytes for Lithium Metal Batteries.” Advanced Functional Materials, vol. 32, no. 25, Apr. 2022, p. 2201465. https://doi.org/10.1002/adfm.202201465.

Found error?

Publisher

Wiley

Journal

Advanced Functional Materials

Quartile SCImago

Quartile WOS

Impact factor

ISSN

1616301X (Print)
16163028 (Electronic)