Advanced Functional Materials, volume 32, issue 28, pages 2201528
Design Unique Air‐Stable and Li–Metal Compatible Sulfide Electrolyte via Exploration of Anion Functional Units for All‐Solid‐State Lithium–Metal Batteries
Publication type: Journal Article
Publication date: 2022-04-14
Journal:
Advanced Functional Materials
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 19
ISSN: 1616301X, 16163028
Electronic, Optical and Magnetic Materials
Electrochemistry
Condensed Matter Physics
Biomaterials
Abstract
The marriage of solid-state sulfide electrolytes (SSSEs) with Li-anode and oxide-based cathodes can multiply the energy density of all-solid-state Lithium–metal batteries (ASSLMBs). However, hydrolysis in the air, reduction at the Li/SSSE interface, and growth of Li-dendrites inside SSSEs collectively block the route of sulfide-based ASSLMBs. Herein, a novel Li2.96P0.98S3.92O0.06-Li3N glass–ceramic electrolyte (GCE) is developed, wherein O and N substitution produce POS33– and Li3N unique functional units enable superior σLi+ 1.58 mS cm–1 at RT. Notably, POS33– units in Li2.96P0.98S3.92O0.06-Li3N excellently prevent the structural degradation against moisture @45–50%. The critical current density of Li2.96P0.98S3.92O0.06–Li3N reaches 1 mA cm–2/1 mAh cm–2 @ RT. Moreover, Li//Li cells realize unprecedented Li-plating/stripping >1000 h at 0.3 mA cm–2/0.3 mAh cm–2 and 0.5 mA cm–2/0.5 mAh cm–2 at RT. ToF-SIMS and depth-X-ray photoelectron spectroscopy (XPS) confirm the formation of Pre-solid-electrolyte interphase (SEI) enriched with thermodynamically stable Li2O and Li3N species at Li/Li2.96P0.98S3.92O0.06–Li3N interface, suppressing the interfacial reactions and growth of Li-dendrites inside Li2.96P0.98S3.92O0.06–Li3N. Furthermore, LiNbO3@NCA/Li2.96P0.98S3.92O0.06–Li3N/Li cells deliver a remarkable initial discharge capacity of 177.3, 177.6, and 177.8 mAh g–1 with 7.50, 16.50, and 21.50 mg cm–2 of NCA loading. Thus, the novel Li2.96P0.98S3.92O0.06–Li3N GCE addresses all key challenging issues and has tremendous potential to be used in sulfide-based high-energy ASSLMBs.
Top-30
Citations by journals
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1 publication, 2.5%
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1 publication, 2.5%
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ChemSusChem
1 publication, 2.5%
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1 publication, 2.5%
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1 publication, 2.5%
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1 publication, 2.5%
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Jiegou Huaxue
1 publication, 2.5%
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Russian Chemical Reviews
1 publication, 2.5%
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1 publication, 2.5%
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1 publication, 2.5%
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1
2
3
4
5
6
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Citations by publishers
5
10
15
20
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Wiley
20 publications, 50%
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Elsevier
8 publications, 20%
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American Chemical Society (ACS)
4 publications, 10%
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Springer Nature
2 publications, 5%
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American Institute of Physics (AIP)
1 publication, 2.5%
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Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 2.5%
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American Association for the Advancement of Science (AAAS)
1 publication, 2.5%
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Royal Society of Chemistry (RSC)
1 publication, 2.5%
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Chinese Academy of Sciences
1 publication, 2.5%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 2.5%
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5
10
15
20
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Ahmad N. et al. Design Unique Air‐Stable and Li–Metal Compatible Sulfide Electrolyte via Exploration of Anion Functional Units for All‐Solid‐State Lithium–Metal Batteries // Advanced Functional Materials. 2022. Vol. 32. No. 28. p. 2201528.
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Ahmad N., Sun S., Yu P., Yang W. Design Unique Air‐Stable and Li–Metal Compatible Sulfide Electrolyte via Exploration of Anion Functional Units for All‐Solid‐State Lithium–Metal Batteries // Advanced Functional Materials. 2022. Vol. 32. No. 28. p. 2201528.
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TY - JOUR
DO - 10.1002/adfm.202201528
UR - https://doi.org/10.1002/adfm.202201528
TI - Design Unique Air‐Stable and Li–Metal Compatible Sulfide Electrolyte via Exploration of Anion Functional Units for All‐Solid‐State Lithium–Metal Batteries
T2 - Advanced Functional Materials
AU - Sun, Shaorui
AU - Ahmad, Niaz
AU - Yang, Wen
AU - Yu, Peiwen
PY - 2022
DA - 2022/04/14 00:00:00
PB - Wiley
SP - 2201528
IS - 28
VL - 32
SN - 1616-301X
SN - 1616-3028
ER -
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@article{2022_Ahmad,
author = {Shaorui Sun and Niaz Ahmad and Wen Yang and Peiwen Yu},
title = {Design Unique Air‐Stable and Li–Metal Compatible Sulfide Electrolyte via Exploration of Anion Functional Units for All‐Solid‐State Lithium–Metal Batteries},
journal = {Advanced Functional Materials},
year = {2022},
volume = {32},
publisher = {Wiley},
month = {apr},
url = {https://doi.org/10.1002/adfm.202201528},
number = {28},
pages = {2201528},
doi = {10.1002/adfm.202201528}
}
Cite this
MLA
Copy
Ahmad, Niaz, et al. “Design Unique Air‐Stable and Li–Metal Compatible Sulfide Electrolyte via Exploration of Anion Functional Units for All‐Solid‐State Lithium–Metal Batteries.” Advanced Functional Materials, vol. 32, no. 28, Apr. 2022, p. 2201528. https://doi.org/10.1002/adfm.202201528.