Advanced Functional Materials, volume 32, issue 28, pages 2201528

Design Unique Air‐Stable and Li–Metal Compatible Sulfide Electrolyte via Exploration of Anion Functional Units for All‐Solid‐State Lithium–Metal Batteries

Niaz Ahmad ¹

Shaorui Sun ²

Peiwen Yu ¹

Wen Yang ¹

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Key Laboratory of Cluster Science of Ministry of Education Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials School of Chemistry and Chemical Engineering, Beijing Institute of Technology 5# Zhongguancun Road, Haidian District Beijing 100081 P. R. China |

Beijing Key Laboratory for Green Catalysis and Separation College of Environmental and Energy Engineering Beijing University of Technology Beijing 100124 P. R. China |

Publication type: Journal Article

Publication date: 2022-04-14

Wiley

Journal: Advanced Functional Materials

Quartile SCImago

Quartile WOS

Impact factor: 19

ISSN: 1616301X, 16163028

DOI: 10.1002/adfm.202201528

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Electronic, Optical and Magnetic Materials

Electrochemistry

Condensed Matter Physics

Biomaterials

Abstract

The marriage of solid-state sulfide electrolytes (SSSEs) with Li-anode and oxide-based cathodes can multiply the energy density of all-solid-state Lithium–metal batteries (ASSLMBs). However, hydrolysis in the air, reduction at the Li/SSSE interface, and growth of Li-dendrites inside SSSEs collectively block the route of sulfide-based ASSLMBs. Herein, a novel Li2.96P0.98S3.92O0.06-Li3N glass–ceramic electrolyte (GCE) is developed, wherein O and N substitution produce POS33– and Li3N unique functional units enable superior σLi+ 1.58 mS cm–1 at RT. Notably, POS33– units in Li2.96P0.98S3.92O0.06-Li3N excellently prevent the structural degradation against moisture @45–50%. The critical current density of Li2.96P0.98S3.92O0.06–Li3N reaches 1 mA cm–2/1 mAh cm–2 @ RT. Moreover, Li//Li cells realize unprecedented Li-plating/stripping >1000 h at 0.3 mA cm–2/0.3 mAh cm–2 and 0.5 mA cm–2/0.5 mAh cm–2 at RT. ToF-SIMS and depth-X-ray photoelectron spectroscopy (XPS) confirm the formation of Pre-solid-electrolyte interphase (SEI) enriched with thermodynamically stable Li2O and Li3N species at Li/Li2.96P0.98S3.92O0.06–Li3N interface, suppressing the interfacial reactions and growth of Li-dendrites inside Li2.96P0.98S3.92O0.06–Li3N. Furthermore, LiNbO3@NCA/Li2.96P0.98S3.92O0.06–Li3N/Li cells deliver a remarkable initial discharge capacity of 177.3, 177.6, and 177.8 mAh g–1 with 7.50, 16.50, and 21.50 mg cm–2 of NCA loading. Thus, the novel Li2.96P0.98S3.92O0.06–Li3N GCE addresses all key challenging issues and has tremendous potential to be used in sulfide-based high-energy ASSLMBs.

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Citations by journals

	1 2 3 4 5 6
Chemical Engineering Journal	Chemical Engineering Journal, 6, 15% Chemical Engineering Journal 6 publications, 15%
Advanced Energy Materials	Advanced Energy Materials, 3, 7.5% Advanced Energy Materials 3 publications, 7.5%
Advanced Materials	Advanced Materials, 3, 7.5% Advanced Materials 3 publications, 7.5%
Advanced Functional Materials	Advanced Functional Materials, 3, 7.5% Advanced Functional Materials 3 publications, 7.5%
Energy Technology	Energy Technology, 2, 5% Energy Technology 2 publications, 5%
ACS applied materials & interfaces	ACS applied materials & interfaces, 2, 5% ACS applied materials & interfaces 2 publications, 5%
Advanced Science	Advanced Science, 2, 5% Advanced Science 2 publications, 5%
Small	Small, 2, 5% Small 2 publications, 5%
Applied Physics Letters	Applied Physics Letters, 1, 2.5% Applied Physics Letters 1 publication, 2.5%
Materials	Materials, 1, 2.5% Materials 1 publication, 2.5%
ACS Applied Energy Materials	ACS Applied Energy Materials, 1, 2.5% ACS Applied Energy Materials 1 publication, 2.5%
Nano Letters	Nano Letters, 1, 2.5% Nano Letters 1 publication, 2.5%
Energy Material Advances	Energy Material Advances, 1, 2.5% Energy Material Advances 1 publication, 2.5%
Energy and Environmental Science	Energy and Environmental Science, 1, 2.5% Energy and Environmental Science 1 publication, 2.5%
Interdisciplinary Materials	Interdisciplinary Materials, 1, 2.5% Interdisciplinary Materials 1 publication, 2.5%
Chemical Record	Chemical Record, 1, 2.5% Chemical Record 1 publication, 2.5%
Batteries & Supercaps	Batteries & Supercaps, 1, 2.5% Batteries & Supercaps 1 publication, 2.5%
ChemSusChem	ChemSusChem, 1, 2.5% ChemSusChem 1 publication, 2.5%
Journal of Alloys and Compounds	Journal of Alloys and Compounds, 1, 2.5% Journal of Alloys and Compounds 1 publication, 2.5%
Journal of Power Sources	Journal of Power Sources, 1, 2.5% Journal of Power Sources 1 publication, 2.5%
Energy & Environmental Materials	Energy & Environmental Materials, 1, 2.5% Energy & Environmental Materials 1 publication, 2.5%
Jiegou Huaxue	Jiegou Huaxue, 1, 2.5% Jiegou Huaxue 1 publication, 2.5%
Russian Chemical Reviews	Russian Chemical Reviews, 1, 2.5% Russian Chemical Reviews 1 publication, 2.5%
Nano Research	Nano Research, 1, 2.5% Nano Research 1 publication, 2.5%
Science China Chemistry	Science China Chemistry, 1, 2.5% Science China Chemistry 1 publication, 2.5%
	1 2 3 4 5 6

Citations by publishers

	5 10 15 20
Wiley	Wiley, 20, 50% Wiley 20 publications, 50%
Elsevier	Elsevier, 8, 20% Elsevier 8 publications, 20%
American Chemical Society (ACS)	American Chemical Society (ACS), 4, 10% American Chemical Society (ACS) 4 publications, 10%
Springer Nature	Springer Nature, 2, 5% Springer Nature 2 publications, 5%
American Institute of Physics (AIP)	American Institute of Physics (AIP), 1, 2.5% American Institute of Physics (AIP) 1 publication, 2.5%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 1, 2.5% Multidisciplinary Digital Publishing Institute (MDPI) 1 publication, 2.5%
American Association for the Advancement of Science (AAAS)	American Association for the Advancement of Science (AAAS), 1, 2.5% American Association for the Advancement of Science (AAAS) 1 publication, 2.5%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 1, 2.5% Royal Society of Chemistry (RSC) 1 publication, 2.5%
Chinese Academy of Sciences	Chinese Academy of Sciences, 1, 2.5% Chinese Academy of Sciences 1 publication, 2.5%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 2.5% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 2.5%
	5 10 15 20

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Ahmad N. et al. Design Unique Air‐Stable and Li–Metal Compatible Sulfide Electrolyte via Exploration of Anion Functional Units for All‐Solid‐State Lithium–Metal Batteries // Advanced Functional Materials. 2022. Vol. 32. No. 28. p. 2201528.

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Ahmad N., Sun S., Yu P., Yang W. Design Unique Air‐Stable and Li–Metal Compatible Sulfide Electrolyte via Exploration of Anion Functional Units for All‐Solid‐State Lithium–Metal Batteries // Advanced Functional Materials. 2022. Vol. 32. No. 28. p. 2201528.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1002/adfm.202201528

UR - https://doi.org/10.1002/adfm.202201528

TI - Design Unique Air‐Stable and Li–Metal Compatible Sulfide Electrolyte via Exploration of Anion Functional Units for All‐Solid‐State Lithium–Metal Batteries

T2 - Advanced Functional Materials

AU - Sun, Shaorui

AU - Ahmad, Niaz

AU - Yang, Wen

AU - Yu, Peiwen

PY - 2022

DA - 2022/04/14 00:00:00

PB - Wiley

SP - 2201528

IS - 28

VL - 32

SN - 1616-301X

SN - 1616-3028

ER -

BibTex |

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BibTex Copy

@article{2022_Ahmad,

author = {Shaorui Sun and Niaz Ahmad and Wen Yang and Peiwen Yu},

title = {Design Unique Air‐Stable and Li–Metal Compatible Sulfide Electrolyte via Exploration of Anion Functional Units for All‐Solid‐State Lithium–Metal Batteries},

journal = {Advanced Functional Materials},

year = {2022},

volume = {32},

publisher = {Wiley},

month = {apr},

url = {https://doi.org/10.1002/adfm.202201528},

number = {28},

pages = {2201528},

doi = {10.1002/adfm.202201528}

}

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Ahmad, Niaz, et al. “Design Unique Air‐Stable and Li–Metal Compatible Sulfide Electrolyte via Exploration of Anion Functional Units for All‐Solid‐State Lithium–Metal Batteries.” Advanced Functional Materials, vol. 32, no. 28, Apr. 2022, p. 2201528. https://doi.org/10.1002/adfm.202201528.

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Wiley

Journal

Advanced Functional Materials

Quartile SCImago

Quartile WOS

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1616301X (Print)
16163028 (Electronic)