Advanced Functional Materials, pages 2209695

A Novel Self‐Assembled Cobalt‐Free Perovskite Composite Cathode with Triple‐Conduction for Intermediate Proton‐Conducting Solid Oxide Fuel Cells

Hua Tong 1
Min Fu 1
Yang Yang 1
Fanglin Chen 2
Zetian Tao 1
Publication typeJournal Article
Publication date2022-09-30
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor19
ISSN1616301X, 16163028
Electronic, Optical and Magnetic Materials
Electrochemistry
Condensed Matter Physics
Biomaterials
Abstract
A traditional composite cathode for proton-conducting solid oxide fuel cells (H-SOFCs) is typically obtained by mixing cathode materials and proton conducting electrolyte of BaCe0.7Y0.2Zr0.1O3–δ (BZCY), providing chemical and thermal compatibility with the electrolyte. Here, a series of triple-conducing and cobalt-free iron-based perovskites as cathodes for H-SOFCs is reported. Specifically, BaCexFe1–xO3–δ (x = 0.36, 0.43, and 0.50) shows various contents of two single phase perovskites with an in situ heterojunction structure as well as triple conductivity by tailoring the Ce/Fe ratios. The cell performance with the optimized BaCe0.36Fe0.64O3–δ (BCF36) cathode composition reaches 1056 mW cm−2 at 700 °C. Moreover, a record cell performance of 1525 mW cm−2 at 700 °C is obtained by modifying the BCF36 cathode microstructure through a spraying method, demonstrating high promise with Co-free cathodes for H-SOFCs.

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Tong H. et al. A Novel Self‐Assembled Cobalt‐Free Perovskite Composite Cathode with Triple‐Conduction for Intermediate Proton‐Conducting Solid Oxide Fuel Cells // Advanced Functional Materials. 2022. p. 2209695.
GOST all authors (up to 50) Copy
Tong H., Fu M., Yang Y., Chen F., Tao Z. A Novel Self‐Assembled Cobalt‐Free Perovskite Composite Cathode with Triple‐Conduction for Intermediate Proton‐Conducting Solid Oxide Fuel Cells // Advanced Functional Materials. 2022. p. 2209695.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1002/adfm.202209695
UR - https://doi.org/10.1002/adfm.202209695
TI - A Novel Self‐Assembled Cobalt‐Free Perovskite Composite Cathode with Triple‐Conduction for Intermediate Proton‐Conducting Solid Oxide Fuel Cells
T2 - Advanced Functional Materials
AU - Tong, Hua
AU - Fu, Min
AU - Yang, Yang
AU - Chen, Fanglin
AU - Tao, Zetian
PY - 2022
DA - 2022/09/30 00:00:00
PB - Wiley
SP - 2209695
SN - 1616-301X
SN - 1616-3028
ER -
BibTex
Cite this
BibTex Copy
@article{2022_Tong,
author = {Hua Tong and Min Fu and Yang Yang and Fanglin Chen and Zetian Tao},
title = {A Novel Self‐Assembled Cobalt‐Free Perovskite Composite Cathode with Triple‐Conduction for Intermediate Proton‐Conducting Solid Oxide Fuel Cells},
journal = {Advanced Functional Materials},
year = {2022},
publisher = {Wiley},
month = {sep},
url = {https://doi.org/10.1002/adfm.202209695},
pages = {2209695},
doi = {10.1002/adfm.202209695}
}
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