Advanced Functional Materials
Superlithiophilic, Ultrastable, and Ionic‐Conductive Interface Enabled Long Lifespan All‐Solid‐State Lithium‐Metal Batteries under High Mass Loading
Guanjie Lu
1
,
Wei Liu
1, 2
,
Zuguang Yang
1
,
Yumei Wang
1, 3
,
WeiKang Zheng
4
,
Rongrui Deng
4, 5
,
Ronghua Wang
4
,
Li Lu
3
,
Chaohe Xu
1, 5
3
National University of Singapore (Chongqing) Research Institute Chongqing 401123 China
|
Publication type: Journal Article
Publication date: 2023-07-25
Journal:
Advanced Functional Materials
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 19
ISSN: 1616301X, 16163028
Electronic, Optical and Magnetic Materials
Electrochemistry
Condensed Matter Physics
Biomaterials
Abstract
Garnet‐type Li6.4La3Zr1.4Ta0.6O12 (LLZTO) suffers from instability against moist air, poor interfacial contact with anode, and serious dendrite issue, which greatly impede its practical application in all‐solid‐state lithium batteries (ASSLBs). Herein, a superlithiophilic, moisture‐resistant, and robust interlayer is demonstrated to overcome these obstacles by in situ forming an AlF3 interlayer on the LLZTO surface. Thanks to the unique property, the AlF3‐modified LLZTO offers a significantly reduced interfacial resistance by more than two orders of magnitude (from 527.5 Ω cm2 for the pristine Li/LLZTO to 1.3 Ω cm2 for the surface‐engineered interface), achieves a critical current density of 1.2 mA cm−2 and long‐term stability of over 4000–4700 h, and endows regulated Li plating/stripping behaviors. Specifically, ASSLBs coupled with LiFePO4 and LiNi0.8Co0.1Mn0.1O2 (NCM811) cathodes can stably charge/discharge over 400 and 100 cycles at 0.5 and 0.2 C at 25 °C, with retentions of >80.0% and Coulombic efficiencies of >99.9%, respectively. Particularly, the NCM811‐based full ASSLB with large mass loading of 8.3 mg cm−2 also delivers a discharge‐specific capacity as high as 199.1 mAh g−1 with good rate capability, even approaching to the liquid cells. This study demonstrates a practical solution to address the interfacial challenges and paves the way for practical progress of ASSLBs.
Top-30
Citations by journals
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2
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Advanced Functional Materials
2 publications, 11.76%
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Angewandte Chemie - International Edition
1 publication, 5.88%
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Angewandte Chemie
1 publication, 5.88%
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Composites Communications
1 publication, 5.88%
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SusMat
1 publication, 5.88%
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Electrochimica Acta
1 publication, 5.88%
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Chemical Engineering Journal
1 publication, 5.88%
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Small
1 publication, 5.88%
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Materials Research Express
1 publication, 5.88%
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ACS Nano
1 publication, 5.88%
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Journal of Colloid and Interface Science
1 publication, 5.88%
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Nature Communications
1 publication, 5.88%
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Russian Chemical Reviews
1 publication, 5.88%
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Interdisciplinary Materials
1 publication, 5.88%
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ACS Applied Energy Materials
1 publication, 5.88%
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Energy Storage Materials
1 publication, 5.88%
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2
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Citations by publishers
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1
2
3
4
5
6
7
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Wiley
7 publications, 41.18%
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Elsevier
5 publications, 29.41%
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American Chemical Society (ACS)
2 publications, 11.76%
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IOP Publishing
1 publication, 5.88%
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Springer Nature
1 publication, 5.88%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 5.88%
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5
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7
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Lu G. et al. Superlithiophilic, Ultrastable, and Ionic‐Conductive Interface Enabled Long Lifespan All‐Solid‐State Lithium‐Metal Batteries under High Mass Loading // Advanced Functional Materials. 2023.
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Lu G., Liu W., Yang Z., Wang Y., Zheng W., Deng R., Wang R., Lu L., Xu C. Superlithiophilic, Ultrastable, and Ionic‐Conductive Interface Enabled Long Lifespan All‐Solid‐State Lithium‐Metal Batteries under High Mass Loading // Advanced Functional Materials. 2023.
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TY - JOUR
DO - 10.1002/adfm.202304407
UR - https://doi.org/10.1002/adfm.202304407
TI - Superlithiophilic, Ultrastable, and Ionic‐Conductive Interface Enabled Long Lifespan All‐Solid‐State Lithium‐Metal Batteries under High Mass Loading
T2 - Advanced Functional Materials
AU - Lu, Guanjie
AU - Liu, Wei
AU - Yang, Zuguang
AU - Wang, Yumei
AU - Zheng, WeiKang
AU - Deng, Rongrui
AU - Wang, Ronghua
AU - Lu, Li
AU - Xu, Chaohe
PY - 2023
DA - 2023/07/25 00:00:00
PB - Wiley
SN - 1616-301X
SN - 1616-3028
ER -
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@article{2023_Lu,
author = {Guanjie Lu and Wei Liu and Zuguang Yang and Yumei Wang and WeiKang Zheng and Rongrui Deng and Ronghua Wang and Li Lu and Chaohe Xu},
title = {Superlithiophilic, Ultrastable, and Ionic‐Conductive Interface Enabled Long Lifespan All‐Solid‐State Lithium‐Metal Batteries under High Mass Loading},
journal = {Advanced Functional Materials},
year = {2023},
publisher = {Wiley},
month = {jul},
url = {https://doi.org/10.1002/adfm.202304407},
doi = {10.1002/adfm.202304407}
}
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