Advanced Materials, volume 31, issue 10, pages 1807243
Lithium-Graphite Paste: An Interface Compatible Anode for Solid-State Batteries
Ji’an Duan
1
,
Wangyan Wu
1
,
Adelaide M Nolan
2
,
Tengrui Wang
1
,
Jiayun Wen
1
,
Chenchen Hu
1
,
Yifei Mo
2
,
Wei Luo
1
,
Yun-Hui Huang
1
Publication type: Journal Article
Publication date: 2019-01-21
Journal:
Advanced Materials
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 29.4
ISSN: 09359648, 15214095
General Materials Science
Mechanical Engineering
Mechanics of Materials
Abstract
All-solid-state batteries (ASSBs) with ceramic-based solid-state electrolytes (SSEs) enable high safety that is inaccessible with conventional lithium-ion batteries. Lithium metal, the ultimate anode with the highest specific capacity, also becomes available with nonflammable SSEs in ASSBs, which offers promising energy density. The rapid development of ASSBs, however, is significantly hampered by the large interfacial resistance as a matched lithium/ceramic interface that is not easy to pursue. Here, a lithium-graphite (Li-C) composite anode is fabricated, which shows a dramatic modification in wettability with garnet SSE. An intimate Li-C/garnet interface is obtained by casting Li-C composite onto garnet-type SSE, delivering an interfacial resistance as low as 11 Ω cm2 . As a comparison, pure Li/garnet interface gives a large resistance of 381 Ω cm2 . Such improvement can be ascribed to the experiment-measured increased viscosity of Li-C composite and simulation-verified limited interfacial reaction. The Li-C/garnet/Li-C symmetric cell exhibits stable plating/striping performance with small voltage hysteresis and endures a critical current density up to 1.0 mA cm-2 . The full cell paired with LiFePO4 shows stable cycle performance, comparable to the cell with liquid electrolyte. The present work demonstrates a promising strategy to develop ceramic-compatible lithium metal-based anodes and hence low-impedance ASSBs.
Top-30
Citations by journals
2
4
6
8
10
12
14
16
18
|
|
Advanced Functional Materials
17 publications, 7.83%
|
|
ACS applied materials & interfaces
16 publications, 7.37%
|
|
Advanced Energy Materials
12 publications, 5.53%
|
|
ACS Applied Energy Materials
9 publications, 4.15%
|
|
Advanced Materials
8 publications, 3.69%
|
|
Journal of Materials Chemistry A
7 publications, 3.23%
|
|
Chemical Engineering Journal
6 publications, 2.76%
|
|
Nano Energy
6 publications, 2.76%
|
|
Small
6 publications, 2.76%
|
|
Rare Metals
5 publications, 2.3%
|
|
Angewandte Chemie
5 publications, 2.3%
|
|
Angewandte Chemie - International Edition
5 publications, 2.3%
|
|
Energy and Environmental Science
5 publications, 2.3%
|
|
Nature Communications
4 publications, 1.84%
|
|
Energy Storage Materials
4 publications, 1.84%
|
|
Nano Letters
4 publications, 1.84%
|
|
Matter
3 publications, 1.38%
|
|
Electrochemical Energy Reviews
3 publications, 1.38%
|
|
ACS Nano
3 publications, 1.38%
|
|
ACS Energy Letters
3 publications, 1.38%
|
|
Energy Technology
3 publications, 1.38%
|
|
Advanced Science
2 publications, 0.92%
|
|
Frontiers in Chemistry
2 publications, 0.92%
|
|
Batteries
2 publications, 0.92%
|
|
Materials Today
2 publications, 0.92%
|
|
Ceramics International
2 publications, 0.92%
|
|
Small Methods
2 publications, 0.92%
|
|
Batteries & Supercaps
2 publications, 0.92%
|
|
Energy & Environmental Materials
2 publications, 0.92%
|
|
2
4
6
8
10
12
14
16
18
|
Citations by publishers
10
20
30
40
50
60
70
80
|
|
Wiley
77 publications, 35.48%
|
|
American Chemical Society (ACS)
45 publications, 20.74%
|
|
Elsevier
37 publications, 17.05%
|
|
Royal Society of Chemistry (RSC)
19 publications, 8.76%
|
|
Springer Nature
15 publications, 6.91%
|
|
Nonferrous Metals Society of China
5 publications, 2.3%
|
|
Multidisciplinary Digital Publishing Institute (MDPI)
3 publications, 1.38%
|
|
Frontiers Media S.A.
2 publications, 0.92%
|
|
Chinese Physical Society
2 publications, 0.92%
|
|
OAE Publishing Inc.
2 publications, 0.92%
|
|
American Institute of Physics (AIP)
1 publication, 0.46%
|
|
Bentham Science
1 publication, 0.46%
|
|
The Electrochemical Society
1 publication, 0.46%
|
|
Tsinghua University Press
1 publication, 0.46%
|
|
University of Science and Technology Beijing
1 publication, 0.46%
|
|
Electrochemical Science Group, University of Belgrade
1 publication, 0.46%
|
|
American Association for the Advancement of Science (AAAS)
1 publication, 0.46%
|
|
Hans Publishers
1 publication, 0.46%
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 0.46%
|
|
10
20
30
40
50
60
70
80
|
- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2019,2020,2021,2022,2023,2024],"ids":[0,0,0,0,0,0],"codes":[0,0,0,0,0,0],"imageUrls":["","","","","",""],"datasets":[{"label":"Citations number","data":[22,59,41,28,35,32],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["10.14","27.19","18.89","12.9","16.13","14.75"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Advanced Functional Materials","ACS applied materials & interfaces","Advanced Energy Materials","ACS Applied Energy Materials","Advanced Materials","Journal of Materials Chemistry A","Chemical Engineering Journal","Nano Energy","Small","Rare Metals","Angewandte Chemie","Angewandte Chemie - International Edition","Energy and Environmental Science","Nature Communications","Energy Storage Materials","Nano Letters","Matter","Electrochemical Energy Reviews","ACS Nano","ACS Energy Letters","Energy Technology","Advanced Science","Frontiers in Chemistry","Batteries","Materials Today","Ceramics International","Small Methods","Batteries & Supercaps","Energy & Environmental Materials"],"ids":[7715,1458,22475,6419,25159,14919,16275,23236,9872,18829,25450,19215,10138,3231,3858,10312,14717,25884,8724,9022,20046,4130,6407,19798,5179,15103,4145,26456,26479],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/4QWA67eqfcfyOiA8Wk7YnqroHFqQbTsmDJUYTCTg_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp"],"datasets":[{"label":"","data":[17,16,12,9,8,7,6,6,6,5,5,5,5,4,4,4,3,3,3,3,3,2,2,2,2,2,2,2,2],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[7.83,7.37,5.53,4.15,3.69,3.23,2.76,2.76,2.76,2.3,2.3,2.3,2.3,1.84,1.84,1.84,1.38,1.38,1.38,1.38,1.38,0.92,0.92,0.92,0.92,0.92,0.92,0.92,0.92],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Wiley","American Chemical Society (ACS)","Elsevier","Royal Society of Chemistry (RSC)","Springer Nature","Nonferrous Metals Society of China","Multidisciplinary Digital Publishing Institute (MDPI)","Frontiers Media S.A.","Chinese Physical Society","OAE Publishing Inc.","American Institute of Physics (AIP)","Bentham Science","The Electrochemical Society","Tsinghua University Press","University of Science and Technology Beijing","Electrochemical Science Group, University of Belgrade","American Association for the Advancement of Science (AAAS)","Hans Publishers","Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii"],"ids":[11,40,17,123,8,1585,202,208,3809,7181,250,39,6916,1836,2262,4568,189,8722,9422],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/4QWA67eqfcfyOiA8Wk7YnqroHFqQbTsmDJUYTCTg_medium.webp","\/storage\/images\/resized\/uHl9M7oE4uFd6rEwxtu87cdHS4Etul2pdLbot8Qu_medium.webp","\/storage\/images\/resized\/0oGA3odz6rRHYyWD8vQnHiPJ8KIaP1PtNoJm7RE1_medium.webp","\/storage\/images\/resized\/ARM4e6URKRsbRZvIF0vFis9DjxGloBjnBYJXbHmZ_medium.webp","\/storage\/images\/resized\/doUaFUZdxUEQjLi1TwZjGHi8HXYNWWSk04dSC6Xh_medium.webp","\/storage\/images\/resized\/s6nfxitVCZUsdJiJZESaAXqdmMJxom8q4Ps6ayL2_medium.webp","\/storage\/images\/resized\/ZBf59wI1SMgSL89rU8cJXRfzrfAz8slfIClYmcuk_medium.webp","","","\/storage\/images\/resized\/s10mcsCV4OAUg9O2KrqOquQC0PhyLMI8hUUkuflM_medium.webp","\/storage\/images\/resized\/RJ5CyToQ8bANAfubYmoLtlA4KJKHWcRsvUmqs5XH_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp"],"datasets":[{"label":"","data":[77,45,37,19,15,5,3,2,2,2,1,1,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[35.48,20.74,17.05,8.76,6.91,2.3,1.38,0.92,0.92,0.92,0.46,0.46,0.46,0.46,0.46,0.46,0.46,0.46,0.46],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartiles":{"type":"bar","data":{"show":true,"labels":[2019,2020,2021,2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,0,0,0,0],"percentage":["0","0","0","0","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,2,0,0,1,0],"percentage":["0","0.92","0","0","0.46","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[0,2,1,2,4,3],"percentage":["0","0.92","0.46","0.92","1.84","1.38"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[21,55,40,20,28,25],"percentage":["9.68","25.35","18.43","9.22","12.9","11.52"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[1,0,0,6,2,4],"percentage":["0.46","0","0","2.76","0.92","1.84"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by SCImago per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartilesWs":{"type":"bar","data":{"show":true,"labels":[2019,2020,2021,2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,2,0,0,2,1],"percentage":["0","0.92","0","0","0.92","0.46"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,1,0,1,2,0],"percentage":["0","0.46","0","0.46","0.92","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[2,2,4,3,2,2],"percentage":["0.92","0.92","1.84","1.38","0.92","0.92"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[19,50,36,18,27,23],"percentage":["8.76","23.04","16.59","8.29","12.44","10.6"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[1,4,1,6,2,6],"percentage":["0.46","1.84","0.46","2.76","0.92","2.76"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by WoS per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Duan J. et al. Lithium-Graphite Paste: An Interface Compatible Anode for Solid-State Batteries // Advanced Materials. 2019. Vol. 31. No. 10. p. 1807243.
GOST all authors (up to 50)
Copy
Duan J., Wu W., Nolan A. M., Wang T., Wen J., Hu C., Mo Y., Luo W., Huang Y. Lithium-Graphite Paste: An Interface Compatible Anode for Solid-State Batteries // Advanced Materials. 2019. Vol. 31. No. 10. p. 1807243.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/adma.201807243
UR - https://doi.org/10.1002/adma.201807243
TI - Lithium-Graphite Paste: An Interface Compatible Anode for Solid-State Batteries
T2 - Advanced Materials
AU - Duan, Ji’an
AU - Wu, Wangyan
AU - Wang, Tengrui
AU - Wen, Jiayun
AU - Hu, Chenchen
AU - Luo, Wei
AU - Nolan, Adelaide M
AU - Mo, Yifei
AU - Huang, Yun-Hui
PY - 2019
DA - 2019/01/21 00:00:00
PB - Wiley
SP - 1807243
IS - 10
VL - 31
SN - 0935-9648
SN - 1521-4095
ER -
Cite this
BibTex
Copy
@article{2019_Duan,
author = {Ji’an Duan and Wangyan Wu and Tengrui Wang and Jiayun Wen and Chenchen Hu and Wei Luo and Adelaide M Nolan and Yifei Mo and Yun-Hui Huang},
title = {Lithium-Graphite Paste: An Interface Compatible Anode for Solid-State Batteries},
journal = {Advanced Materials},
year = {2019},
volume = {31},
publisher = {Wiley},
month = {jan},
url = {https://doi.org/10.1002/adma.201807243},
number = {10},
pages = {1807243},
doi = {10.1002/adma.201807243}
}
Cite this
MLA
Copy
Duan, Ji’an, et al. “Lithium-Graphite Paste: An Interface Compatible Anode for Solid-State Batteries.” Advanced Materials, vol. 31, no. 10, Jan. 2019, p. 1807243. https://doi.org/10.1002/adma.201807243.