Advanced Materials, volume 35, issue 26, pages 2211461
Zinc Single‐Atom Regulated Hard Carbons for High Rate and Low Temperature Sodium Ion Batteries
Zhixiu Lu
1
,
Jing Wang
2
,
Wuliang Feng
1
,
Xiuping Yin
1
,
Xiaochen Feng
1
,
Shengyu Zhao
1
,
Caixia Li
1
,
Ruixiao Wang
1
,
Qiu-An Huang
1
,
Yufeng Zhao
1
Publication type: Journal Article
Publication date: 2023-05-07
Journal:
Advanced Materials
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 29.4
ISSN: 09359648, 15214095
General Materials Science
Mechanical Engineering
Mechanics of Materials
Abstract
Hard carbons, as one of the most commercializable anode materials for sodium‐ion batteries (SIBs), have to deal with the trade‐off between the rate capability and specific capacity or initial Columbic efficiency (ICE), and the fast performance decline at low temperature (LT) remains poorly understood. Here, a comprehensive regulation on the interfacial/bulk electrochemistry of hard carbons through atomic Zn doping is reported, which demonstrates a record‐high reversible capacity (546 mAh g−1), decent ICE (84%), remarkable rate capability (140 mAh g−1 @ 50 A g−1), and excellent LT capacity (443 mAh g−1 @ −40 °C), outperforming the state‐of‐the‐art literature. This work reveals that the Zn doping can generally induce a local electric field to enable fast bulk Na+ transportation, and meanwhile catalyze the decomposition of NaPF6 to form a robust inorganic‐rich solid‐electrolyte interphase, which elaborates the underlying origin of the boosted electrochemical performance. Importantly, distinguished from room temperature, the intrinsic Na+ migration/desolvation ability of the electrolyte is disclosed to be the crucial rate‐determining factors for the SIB performance at LT. This work provides a fundamental understanding on the charge‐storage kinetics at varied temperatures.
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5
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1 publication, 1.22%
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OAE Publishing Inc.
1 publication, 1.22%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Lu Z. et al. Zinc Single‐Atom Regulated Hard Carbons for High Rate and Low Temperature Sodium Ion Batteries // Advanced Materials. 2023. Vol. 35. No. 26. p. 2211461.
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Lu Z., Wang J., Feng W., Yin X., Feng X., Zhao S., Li C., Wang R., Huang Q., Zhao Y. Zinc Single‐Atom Regulated Hard Carbons for High Rate and Low Temperature Sodium Ion Batteries // Advanced Materials. 2023. Vol. 35. No. 26. p. 2211461.
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TY - JOUR
DO - 10.1002/adma.202211461
UR - https://doi.org/10.1002/adma.202211461
TI - Zinc Single‐Atom Regulated Hard Carbons for High Rate and Low Temperature Sodium Ion Batteries
T2 - Advanced Materials
AU - Lu, Zhixiu
AU - Wang, Jing
AU - Feng, Wuliang
AU - Yin, Xiuping
AU - Feng, Xiaochen
AU - Zhao, Shengyu
AU - Li, Caixia
AU - Wang, Ruixiao
AU - Huang, Qiu-An
AU - Zhao, Yufeng
PY - 2023
DA - 2023/05/07 00:00:00
PB - Wiley
SP - 2211461
IS - 26
VL - 35
SN - 0935-9648
SN - 1521-4095
ER -
Cite this
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@article{2023_Lu,
author = {Zhixiu Lu and Jing Wang and Wuliang Feng and Xiuping Yin and Xiaochen Feng and Shengyu Zhao and Caixia Li and Ruixiao Wang and Qiu-An Huang and Yufeng Zhao},
title = {Zinc Single‐Atom Regulated Hard Carbons for High Rate and Low Temperature Sodium Ion Batteries},
journal = {Advanced Materials},
year = {2023},
volume = {35},
publisher = {Wiley},
month = {may},
url = {https://doi.org/10.1002/adma.202211461},
number = {26},
pages = {2211461},
doi = {10.1002/adma.202211461}
}
Cite this
MLA
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Lu, Zhixiu, et al. “Zinc Single‐Atom Regulated Hard Carbons for High Rate and Low Temperature Sodium Ion Batteries.” Advanced Materials, vol. 35, no. 26, May. 2023, p. 2211461. https://doi.org/10.1002/adma.202211461.