Advanced Synthesis and Catalysis

, volume 351 , issue 9 , pages 1412-1422

Effective Chiral Ferrocenyl Phosphine-Thioether Ligands in Enantioselective Palladium-Catalyzed Allylic Alkylations

Hong Yee Cheung

W. X. Yu

Terry T.-L. Au-Yeung

Zhongyuan Zhou

Albert S. Chan

Publication type: Journal Article

Publication date: 2009-06-03

Wiley

Advanced Synthesis and Catalysis

scimago Q1

wos Q1

SJR: 0.930

CiteScore: 8.0

Impact factor: 4.0

ISSN: 16154150, 16154169

DOI: 10.1002/adsc.200900086

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General Chemistry

Abstract

Chiral ferrocene-derived phosphine-thioether mixed donor ligands supported by heterocycles effected the palladium-catalyzed enantioselective allylic alkylations with excellent yields and enantioselectivities (up to 96% ee). With cyclic and unsymmetrical allylic acetates as substrate, the corresponding alkylated products with enantioselectivities up to 87% ee were obtained. Based on X-ray crystallographic and NMR studies, the origin of the observed enantioselectivities is discussed.

Found

3 citations

Gavrilov Konstantin

DSc in Chemistry, professor

149 publications, 1 766 citations

h-index: 20

Ryazan State University named after S. A. Esenin

Research interests

Asymmetric metal complex catalysis

Asymmetric synthesis

Complex formation

3 citations

Zamilatskov Ilya

🥼 🤝

PhD in Chemistry

64 publications, 472 citations

h-index: 11

A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences

Research interests

Organic Chemistry

2 citations

Tyurin Vladimir

🥼 🤝

PhD in Chemistry

71 publications, 1 818 citations, 7 reviews

h-index: 15

A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences

Supramolecular chemistry

1 citation

Trunina Valeria

12 publications, 55 citations

h-index: 5

Ryazan State University named after S. A. Esenin

Research interests

Complex formation

Organic synthesis

Synthesis of chiral phosphorus-containing ligands

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GOST |

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GOST Copy

Cheung H. Y. et al. Effective Chiral Ferrocenyl Phosphine-Thioether Ligands in Enantioselective Palladium-Catalyzed Allylic Alkylations // Advanced Synthesis and Catalysis. 2009. Vol. 351. No. 9. pp. 1412-1422.

GOST all authors (up to 50) Copy

Cheung H. Y., Yu W. X., Au-Yeung T. T., Zhou Z., Chan A. S. Effective Chiral Ferrocenyl Phosphine-Thioether Ligands in Enantioselective Palladium-Catalyzed Allylic Alkylations // Advanced Synthesis and Catalysis. 2009. Vol. 351. No. 9. pp. 1412-1422.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1002/adsc.200900086

UR - https://doi.org/10.1002/adsc.200900086

TI - Effective Chiral Ferrocenyl Phosphine-Thioether Ligands in Enantioselective Palladium-Catalyzed Allylic Alkylations

T2 - Advanced Synthesis and Catalysis

AU - Cheung, Hong Yee

AU - Yu, W. X.

AU - Au-Yeung, Terry T.-L.

AU - Zhou, Zhongyuan

AU - Chan, Albert S.

PY - 2009

DA - 2009/06/03

PB - Wiley

SP - 1412-1422

IS - 9

VL - 351

SN - 1615-4150

SN - 1615-4169

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2009_Cheung,

author = {Hong Yee Cheung and W. X. Yu and Terry T.-L. Au-Yeung and Zhongyuan Zhou and Albert S. Chan},

title = {Effective Chiral Ferrocenyl Phosphine-Thioether Ligands in Enantioselective Palladium-Catalyzed Allylic Alkylations},

journal = {Advanced Synthesis and Catalysis},

year = {2009},

volume = {351},

publisher = {Wiley},

month = {jun},

url = {https://doi.org/10.1002/adsc.200900086},

number = {9},

pages = {1412--1422},

doi = {10.1002/adsc.200900086}

}

MLA

Cite this

MLA Copy

Cheung, Hong Yee, et al. “Effective Chiral Ferrocenyl Phosphine-Thioether Ligands in Enantioselective Palladium-Catalyzed Allylic Alkylations.” Advanced Synthesis and Catalysis, vol. 351, no. 9, Jun. 2009, pp. 1412-1422. https://doi.org/10.1002/adsc.200900086.

Publisher

Wiley

Journal

Advanced Synthesis and Catalysis

scimago Q1

wos Q1

SJR

0.930

CiteScore

8.0

Impact factor

4.0

ISSN

16154150 (Print)

16154169 (Electronic)